In Catalonia (northeast Spain), a monitoring program was carried out to determine methyl tert.-butyl ether (MTBE), its main degradation products, tert.-butyl alcohol (TBA), tert.-butyl formate (TBF), and other gasoline additives, the oxygenate dialkyl ethers ethyl tert.-butyl ether, tert.-amyl methyl ether and diisopropyl ether and the aromatic compounds benzene, toluene, ethylbenzene and xylen...

In this study, evidence for two novel metabolic processes catalyzed by a filamentous fungus, Graphium sp. strain ATCC 58400, is presented. First, our results indicate that this Graphium sp. can utilize the widely used solvent diethyl ether (DEE) as the sole source of carbon and energy for growth. The kinetics of biomass accumulation and DEE consumption closely followed each other, and the molar...

We studied customer exposure during refueling by collecting air samples from customers' breathing zone. The measurements were carried out during 4 days in summer 1996 at two Finnish self-service gasoline stations with "stage I" vapor recovery systems. The 95-RON (research octane number) gasoline contained approximately 2.7% methyl tert-butyl ether (MTBE), approximately 8.5% tert-amyl methyl eth...

Growth of Aquincola tertiaricarbonis L108 on the fuel oxygenates methyl tert-butyl ether (MTBE), ethyl tert-butyl ether (ETBE) and tert-amyl methyl ether (TAME), as well as on their main metabolites tert-butyl alcohol (TBA), tert-amyl alcohol (TAA) and 2-hydroxyisobutyrate (2-HIBA) was systematically investigated to characterize the range and rates of oxygenate degradation by this strain. The e...

A dynamic modeling approach was used to estimate in-situ model parameters, which describe the degradation of methyl tert-butyl ether (MTBE) in a laboratory packed bed reactor. The measured dynamic response of MTBE pulses injected at the reactor's inlet was analyzed by least squares and parameter response surface methodologies. Response surfaces were found to be statistically significant and thu...

Methyl tertiary butyl ether (MTBE) (CAS No. 1634-04-4) is a volatile organic compound used almost exclusively as an oxygenate in unleaded gasoline to improve combustion efficiency. In the past it also had limited use as a therapeutic drug for dissolving cholesterol gallbladder stones. Currently, MTBE is added at 11% by volume to almost all of the gasoline used in California, although on March 2...

Methyl tert-Butyl Ether (MTBE) was first added to gasoline in Europe in 1973 to replace lead as an anti-knocking agent and as an octane enhancer (CAL-EPA, 1998). U.S. EPA approved it as a blending component in the U.S. in 1979, to eliminate the use of leaded gasoline. Typical MTBE levels used by refiners were around 2-3% by volume, blended in different proportions to achieve performance standards.

Pervaporation removal of methyl tert-butyl ether (MTBE) from dilute aqueous solutions was demonstrated using ceramic-supported polymer (CSP) membranes. These membranes were created by the free radical graft polymerization of vinyl acetate onto a vinyl trimethoxysilaneactivated porous silica substrate having a native average pore size of 500 Å. The resulting membranes consisted of poly(vinyl ace...

Methyl tert-butyl ether (MTBE) is widely used as a gasoline additive with toxicity and carcinogenicity, has caused environmental pollution worldwide. Biodegradation promising method for the removal of MTBE from contaminated sites. In this paper, three strains high adaptability different degrading characteristics to were cultured. The kinetic models established systematically simulate biodegrada...