The isothermal isotopic exchange reaction of O2 with 16O of chromium(VI) oxide supported on zirconia, alumina, and titania has been investigated with in situ laser Raman spectroscopy. The isotopic exchange reaction is dependent on the support type, the Cr loading, and the reaction temperature. Complete isotopic exchange of chromium(VI) oxide with O2 is difficult to achieve and requires several ...

The potential of carbon nanotubes (CNT) supported cobalt catalysts for Fischer-Tropsch (FT) reaction is shown. Using the wet impregnation method cobalt on carbon nanotubes catalysts were prepared with cobalt loading varying from 15 to 45 wt. %. The catalysts are characterized by different methods including: BET physisorption, X-ray diffraction, hydrogen chemisorption, and temperature-progra...

In this study, hydrothermal synthesis was used to prepare α-Ni(OH) 2 , which is a steady-state photocatalytic material. Furthermore, ball milling for the 1:1 loading of with nano-alumina (Al O 3 ), hexagonal boron nitride (h-BN), and activated carbon (AC). The performances these four materials in degradation fracturing flowback fluid were investigated under synergistic catalytic effect ozone. r...

PURPOSE The purpose of the present study was to evaluate the flexural strength of the joint between glass-infiltrated alumina frames and the experimental adjusting agent (MA modifier) that contains alumina and magnesia. METHODS A commercially available adjusting agent (Optimizer), a slurry of alumina powder (Alumina modifier), and a bulk specimen (joint-free alumina) were used as controls. Be...

The article presents the results of studying effect modifying additives CaAl2O4 (CA) and CaAl4O7 (CA2), as well boric acid on processes phase formation clinker minerals. calculation content raw materials in charge is carried out taking into account production high-alumina with participation Al2O3 71–72 wt.% CaO 27–28 wt.%. In accordance state diagram CaO–Al2O3 system, mass amount accumulates tw...

Ceramic membrane composites consisting of a coarse porous a-alumina or two-layer porous alumina membrane support and an oxygen semipermeable gas tight thin (0.2-5 pm) yttria stabilized zirconia (YSZ) film are prepared by the electrochemical vapor deposition (EVD) method. The minimum gastight thickness of the YSZ films depends strongly on the average pore size of the support on which the films a...

In this study, catalysts for fatty acid methyl esters (FAME or biodiesel) synthesis with K2CO3 as the active component on an alumina/silica support were synthesized using the sol–gel method, which was followed by drying the “dense” wet gels with supercritical carbon dioxide to obtain the aerogels. The prepared catalysts were characterized by XRD analysis, FTIR spectroscopy and N2 physisorption ...

in the present investigation surface modification of silica nanoparticles by alumina was carried out by sol-gel process. fourier transform infrared (ftir) and x-ray fluorescence (xrf) confirmed the synthesis of silica and the surface modification as alumina is anchored to silica surface. field emission scanning electron microscopy (fesem) and transmission electron microscopy (tem) investigation...

Solid state nanoporous membranes show great potential as support structures for biointerfaces. In this paper, we present a technique for fabricating nanoporous alumina membranes under constant-flow conditions in a microfluidic environment. This approach allows the direct integration of the fabrication process into a microfluidic setup for performing biological experiments without the need to tr...