The kinetics of the transmetalation reaction between trans-[PdCl(C6Cl2F3)(PPh3)2] and [ZnMeCl(THF)2] shows a complex dependence on [PPh3] for rate formation different products: cis trans-[Pd(C6Cl2F3)Me(PPh3)2], trans-[PdClMe(PPh3)] (which further reacts with [ZnClMe(THF)2]), [Zn(C6Cl2F3)Cl(THF)2]. To better understand system reactions trans-[Pd(C6Cl2F3)Me(PPh3)2] [ZnCl2(THF)2] (the retro-transm...

In this study, the facile and sustainable synthesis of highly microporous carbons is explored to reduce extensive use harsh activating agents solvents. The role potassium citrate (PC) as a greener agent in addition conventional ZnCl2 investigated mechanochemical solvent-free preparation carbon materials from chestnut tannin (CT), biomass-type precursor. A small amount chemical activator coupled...

In the mononuclear title complex, [ZnCl2(C15H16N4O)], the Zn(II) cation is five-coordinated in a strongly distorted square-pyramidal environment by two Cl(-) anions and a neutral tridentate Schiff base ligand. The Zn(II) cation is chelated by the carbonyl O atom, the imine N atom and the pyridine N atom, which causes a slight loss of planarity for the ligand; the dihedral angle between the arom...

The economic amide base lithium dicyclohexylamide (Cy2NLi) allows fast and convenient (40 s, 0 °C) in situ trapping flow metalations of a broad range of functionalized arenes, heteroarenes and acrylate derivatives in the presence of various metal salts (ZnCl2·2LiCl, MgCl2, LaCl3·2LiCl). The resulting Zn-, Mg- or La-organometallic intermediates are trapped with various electrophiles in high yiel...

The fertilization rate of mouse gametes in a Krebs-Ringer bicarbonate medium was 60%. The rate fell to 0% when 250 \g=m\M-ZnCl2 was added, but MgCl2, CaCl2, MnCl2, FeCl2 and CuCl2 (each at 250 \g=m\M)had no effect. The inhibitory effect of Zn2+ was not evident if the spermatozoa or eggs were preincubated with Zn2+ or if previously capacitated spermatozoa were used. The Zn2+ is thought to act by...

The effects of varying concentrations of Mn2* on the absorption of divalent cations, viz., Ca2+ and Zn2+ from 2 concentrations were studied. Mn2+ at all concentrations tested were inhibitory to Ca2+ uptake from 0.1 and 5 mM CaCl2 . However, when Ca2+ uptake was measured at concentrations ranging from 0.05 to 10 mM CaCl2, MnCl2 only at high concentration of 5 mM, inhibited Ca ab­ sorption. Zn2+ ...