The chemical behavior in an aqueous medium of a natural zeolitic material, NZ (mainly consisting in crystals of the zeolites clinoptilolite/heulandite) has been studied through electrochemical techniques, complemented by atomic absorption spectrometry. The time dependence of the conductivity of the aqueous medium in the presence of NZ, showed a steep increase at the beginning followed by a slow...

It is now well established that even though Pd supported on acidic zeolites is highly selective for CH4-SCR, zeolitic structures are susceptible to dealumination under hydrothermal environments. In this contribution, we have investigated the ability of non-zeolitic acidic materials to promote the SCR selectivity and stability in the presence of H2O and SO2. The results of catalytic activity mea...

The fracture mechanism of zeolitic imidazolate framework (ZIF) glasses is revealed to be associated with bond switching organic linkers around central Zn nodes. more pronounced for ZIF smaller linkers.

background and objectives : zeolite is a group of anionic hydrated aluminosilicates with a tridimensional structure which has great implications in remediation of water, sediment and soil resources. the present research aims at physicochemical investigation, clay mineralogy and micromorphology of soils along rafsanjan-sarcheshmeh lithotoposequence, southeastern iran. materials and methods: the ...

The catalytic behavior of Brønsted acid sites in three acidic zeolite materials (one MWW and two MFI zeolites) containing dual meso-/microporosity was studied using ethanol dehydration and monomolecular conversion of propane and isobutane as probe reactions. The meso-/microporous MWW zeolite, MCM-36 or pillared MWW, consists of a zeolitic layer structure, with independent microporosity and meso...