Addressing the direct control of surface wettability has been a significant challenge for a variety of applications from self-cleaning surfaces to phase-change applications. Surface wettability has been traditionally modulated by installing surface nanostructures or changing their chemistry. Among numerous nanofabrication efforts, the chemical oxidation method is considered a promising approach...

  In oil industry, spontaneous imbibition is an important phenomenon in recovery from fractured reservoirs which can be defined as spontaneous uptake of a wetting fluid into a porous solid. Spontaneous imbibition involves both cocurrent and countercurrent flows. When a matrix block is partially covered by water, oil recovery is dominated by cocurrent imbibition i.e. the production of non wettin...

We investigate theoretically the wetting properties of cholesteric liquid crystals at a planar substrate. If the properties of substrate and of the interface are such that the cholesteric layers are not distorted, the wetting properties are similar to those of a nematic liquid crystal. If, on the other hand, the anchoring conditions force the distortion of the liquid crystal layers the wetting ...

Interfaces are essential in electrochemical processes, providing a critical nanoscopic design feature for composite electrodes used in Li-ion batteries. Understanding the structure, wetting and mobility at nano-confined interfaces is important for improving the efficiency and lifetime of electrochemical devices. Here we use a Surface Forces Apparatus to quantify the initial wetting of nanometre...

We study the solvent-annealing-induced nanowetting in templates using porous anodic aluminum oxide membranes. The morphology of polystyrene and poly(methyl methacrylate) nanostructures can be controlled, depending on whether the swollen polymers are in the partial or complete wetting regimes, which are characterized by the spreading coefficient. When the swollen polymers are in the partial wett...

In recent experiments, a sequence of changes in the wetting state (‘wetting transitions’) has been observed upon increasing the temperature in systems consisting of pentane on pure water and of hexane on brine. In this sequentialwetting scenario, there occurs a first-order transition from a partial-wetting state, in which only a microscopically thin film of adsorbate is present on the substrate...

We consider the wetting transition in the framework of an effective interface model of gradient type, in dimension 2 and higher. We prove pathwise estimates showing that the interface is localized in the whole thermodynamically-defined partial wetting regime considered in earlier works. Moreover, we study how the interface delocalizes as the wetting transition is approached. Our main tool is re...

We investigate the interfacial electro-chemical-hydrodynamics of an incompressible immiscible binary fluid system that moves in a narrow fluidic channel under time-periodic electroosmotic effects. We apply an alternating electrical voltage that sets the binary fluids in motion along the channel, whereas the channel walls are lined with chemical patch to alter the wetting characteristics of the ...