نتایج جستجو برای: voltammetric behavior
تعداد نتایج: 621863 فیلتر نتایج به سال:
The voltammetric study of the lactic acid reduction was performed in media suitable for yeast growth, using platinum microelectrodes. The decrease of the voltammetric peak current from square wave voltammetry, ∆Ip, in cultures of the yeasts Candida utilis and Saccharomyces cerevisiae was related to both the growth time and cellular biomass. Either the imposed variations of medium composition or...
Methods for edible oil quality detection mainly have conductivity and peroxide acid value, but as for currently blending edible detection, the effect of these methods is not satisfied. In this study, we propose a cluster algorithm based on artificial fish swarm improvement to detect edible oil by voltammetric electronic tongue. It can optimize the cluster centers value and the initial value. Th...
We report the direct electrochemistry of cytochrome c at screen printed graphite electrodes which exhibits quasi-reversible voltammetric responses without the need for any chemical or electrochemical pre-treatment, use of mediators or nanomaterials. Through voltammetric studies and X-ray photoelectron spectroscopy (XPS) it is shown that carbonyl and carboxylic surface oxygenated species likely ...
The voltammetric characteristics of bismuth(III)-oxinate in chloroform at the mercury electrode were investigated and a quasi-reversible behavior for Bi(III) oxinate reduction was confirmed. Preceded by the extraction of Bi(III) oxinate in chloroform, differential pulse polarography was developed in the extracts for determination of the trace-bismuth. The linear range of the calibration gra...
The electrocatalytic oxidation of captopril (CAP) was studied by modified carbon nanotubes paste electrode in the presence of isoproterenol (ISPT) using cyclic voltammetry (CV), chronoamperometry and square wave voltammetry (SWV). Also, the values of catalytic rate constant (k), and electron transfer coefficient (α) for CAP were calculated. The mechanism of CA electrochemical behavior at the mo...
A new voltammetric sensor is proposed for the determination of bisphenol A, using a glassy carbon electrode (GCE) modified with Fe3O4/graphene oxide (GO) nanocomposite. The modification surface was performed by dispersion drop-casting. electrochemical behavior evaluated cyclic voltammetry (CV). oxidation peak observed during anodic potential scan at potentials 0.45 V. Higher currents (Ipa) wer...
This paper describes the development of a dual-channel microchip in a dual-parallel electrode configuration for voltammetric characterization of analytes in real time. The microchip system contains two distinct separation channels, each having a platinum working electrode set at a different potential. Two separate electropherograms were recorded and current ratios were generated based on the cu...
This paper aims at the study of Pt electrode ability to act as working electrode in cyclic voltammetric sulphite assay. The analytical signal is represented by the intensity measured for the voltammetric peak, that corresponds to analyte anodic oxidation. The measured peak intensity depends linearly on sulphite concentration within the range 0.031 g/L – 4 g/L. The assay is characterized by a li...
Voltammetric detection of the toxic Zn ion was investigated using a fluorine-doped graphite pencil electrode (FPE). It is notable from the study that pencils were used as reference and working electrodes. In all the experiments, a clean seawater electrolyte solution was used to yield good results. The analytical working range was attained to 10 μgL(-1). The optimized voltammetric condition was ...
The presence of trace metal cadmium assay was investigated with a copper immobilized on a graphite carbon electrode (GPC), the modified property of which was determined with handheld voltammetric systems. Following the determination of the analytical stripping conditions of 0.45 V amplitude, 30 Hz frequency, -1.4 V initial potential, and 4.0 mV increment potential, only a 60-s experimental accu...
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