Several reports have demonstrated biotransformation of tetrachloroethylene at low concentrations under strict anaerobic conditions by sequential reductive dechlorination (Fathepure and Boyd, 1988a; Freedman and Gosset, 1989). During this biodegradation, trichloroethylene (TCE), 1,1dichloroethylene, vinylidene chloride (DCE), and vinyl chloride (VC) are the intermediate products ; ethene or etha...

Functionalized vinyl pinacol boronates suitable for Suzuki cross-coupling reactions are synthesized using ruthenium-catalyzed olefin cross-metathesis of 1-propenyl pinacol boronate and various alkenes, including functionalized and 1,1-disubstituted alkenes. The resultant boronate cross products are stereoselectively transformed into predominantly Z-vinyl bromides and E-vinyl iodides. The vinyl ...

Arylalkynes can be converted into α-diketones with the use of a copper catalyst, and also be transformed into vinyl acetates under metal-free conditions, both in the presence of PhI(OAc)2 as an oxidant at room temperature. A series of substituted α-diketones were prepared in moderate to good yields. A variety of vinyl halides could be regio- and stereo-selectively synthesized under mild conditi...

flory fox, kurata-stockmayer, berry, inagaki-suzuki-kurata, stockmayer-fixman and ahmad-baloch methods based on the excluded volume theory have been applied to poly(vinyl chloride)-cyclohexanone system to obtain kq and the radius of gyration. a discussion on the reliability of these methods is given. the stockmayer-fixman and ahmad-baloch methods are found to be equally applicable.

Fluoroethene (FE) is a stable molecule in aqueous solution and its aerobic transformation potentially yields F-. This work evaluated if FE is a suitable surrogate for monitoring aerobic vinyl chloride (VC) utilization or cometabolic transformation. Experiments were carried out with three isolates, Mycobacterium strain EE13a, Mycobacterium strain JS60, and Nocardioides strain JS614 to evaluate i...

S everal recent reports,12 and one in this issue (see page 828), have contributed new observations on pulmonary disease in vinyl chloride (VC ) -and polyvinyl chloride (PVC) -exposed patients. Earlier reports, a few even preceding the identification in 1974 of vinyl chloride as a human carcinogen (with hemangiosarcoma of the liver the marker tumor, but most probably not the only tumor), had cen...

This paper investigates distribution behaviour of the carcinogenic compound vinyl chloride (VC) under semi-natural conditions in a three-phase system (air, water, and aquifer material). A stainless steel column was fi lled with quaternary aquifer material (gritty sand) from a contaminated site (Bitterfeld, Germany). VCcontaminated water with a defi ned concentration was prepared and pumped in s...

Neoplastic effects of vinyl chloride were studied in lungs of 27 mice exposed to vinyl chloride monomer at 2500 and 6000 ppm for 5 and 6 months (large doses and long-term exposure). Pulmonary tumors were observed in 26 of 27 experimental animals. Light microscopy showed the tumors to be multiple and arranged in either tubulo-papillary or adenomatous formations. Although occasional mitotic divis...

Novel LaOCl/LaCl3 catalysts have been discovered that enable the production of vinyl chloride monomer from ethane. An ethane-based process would result in both capital savings and raw materials savings when compared to the current most effective vinyl technology. These materials are unique in the world of chlorination/oxychlorination as the mechanism for chlorination over LaOCl/LaCl3 occurs on ...