the stereospecific polymerization of conjugated dienes began in 1954 with the first catalysts obtained by combining ticl4 or ticl3 with aluminum-alkyls, i.e. the catalytic systems previously employed for ethylene and propylene polymerizations. subsequently, many other catalytic systems were obtained and examined by a combination of transition metal or lanthanide compounds with appropriate alkyl...

This Perspective presents recent advances in macromolecular engineering enabled by ATRP. They include the fundamental mechanistic and synthetic features of ATRP with emphasis on various catalytic/initiation systems that use parts-per-million concentrations of Cu catalysts and can be run in environmentally friendly media, e.g., water. The roles of the major components of ATRP--monomers, initiato...

Various human illnesses, including several types of cancer and infectious diseases, are related to changes in the cellular redox homeostasis. During the last decade, several approaches have been explored which employ such disturbed redox balances for the benefit of therapy. Compounds able to modulate the intracellular redox state of cells have been developed, which effectively, yet also selecti...

Solid acid catalysts are becoming of great importance within the chemical industry and their acidity is of great interest, as this determines their application, plus many of their catalytic properties can also be directly related with their acidity. There has been a drive towards heterogeneous solid acid catalysts because of the environmental concerns with safe handling and disposal of mineral ...

Catalyst activity and performance are the most important factors for selecting a catalyst in different processes. The Fischer-Tropsch synthesis is a very important synthesis that extensive action has been taken place to increase the activity of its catalysts in the recent century. Deactivation of the catalysts of the process is influenced by many factors, among which coking and sintering have c...

The refining industry is currently undergoing its most serious challenge in recent times, since cleaner fuels are gradually introduced in many markets. Middle East countries still have less history than Europe, Japan or the USA when it comes to clean fuels, but the trend is there, which will eventually increase the demand for hydroprocessing catalysts. On the other hand, more sophisticated cata...