This paper includes the significant on-site experience of the authors related to problems faced in amine systems with fresh amine and their possible solutions in phases#2&3 of South Pars gas                complex. The amine system was designed as a closed circuit system with the primary objective of removing H2S, CO2, and other acidic components from gaseous hydrocarbon streams. Amine plant op...

The title compound, C(24)H(21)N(3)O, was prepared by the reaction of (Z)-2-(1H-indol-3-ylmethyl-ene)-1-aza-bicyclo-[2.2.2]octan-3-one with α-bromo-p-toluonitrile, under phase-transfer catalytic (PTC) conditions using triethyl-benzyl-ammonium chloride and 50% w/v aqueous NaOH solution in dichloro-methane. The crystal structure indicates the presence of a double bond with Z geometry connecting th...

The title co-crystal, C(6)H(12)N(2)·C(6)H(6)O(2), is composed of neutral resorcinol and triethyl-enediamine mol-ecules in which the resorcinol mol-ecules came from the in situ deca-rboxylation of 2,4-dihy-droxy-benzoic acid. In the crystal, the components are connected by O-H⋯N hydrogen bonds, forming a chain in the b-axis direction.

A simple and efficient one pot synthesis of 2-amino-4H-chromen-4-yl phosphonate derivatives has been accomplished by the condensation of salicylaldehyde, malononitrile/ethylcyanoacetate and triethyl phosphite/trimethyl phosphite in the presence of molecular iodine as catalyst in water at room temperature. All the reactions were very clean and the products were obtained in very good to excellent...

A practical method was elaborated for the synthesis of (aminomethylene)bisphosphine oxides comprising the catalyst- and solvent-free microwave-assisted three-component condensation of primary amines, triethyl orthoformate and two equivalents of diphenylphosphine oxide. The method is also suitable for the preparation of (aminomethylene)bisphosphonates using (MeO)2P(O)H/(MeO)3CH or (EtO)2P(O)H/(E...

Apart from its numerous biological activities like antidiabetic, anti-inflammatory, antimicrobial, pyrazine moiety plays an important role in luminescent materials. Its role in luminescent materials is due to its highly electron deficient nature specially when it is in the centre along the mainstay of extended π-conjugated systems. Similarly, new liquid crystalline compounds are being made cons...

Metal-catalysed reactions are ubiquitous in organic chemistry and represent a modern research area. In the last years considerable progress was achieved in the field of palladium-catalysed C-Ccoupling. A high number of publications as well as a great amount of reviews and books documented the progress and is reflected in reactions names after Heck, Sonogashira, Stille or Suzuki. Reactions of th...

A simple, rapid, precise, accurate, sensitive and time consuming reverse phase high performance liquid chromatography (RP-HPLC) and spectrophotometric method for simultaneous estimation of atorvastatin and amlodipine in pharmaceutical dosage forms have been developed and validated. Drug was resolved on a C18 column (Phenomenex phenyl hexyl column, 250mm* 4.6mm i.d, 5um). Utilizing mobile phase ...