Most P2-type layered oxides exhibit Na(+)/vacancy-ordered superstructures because of strong Na(+)-Na(+) interaction in the alkali metal layer and charge ordering in the transition metal layer. These superstructures evidenced by voltage plateaus in the electrochemical curves limit the Na(+) ion transport kinetics and cycle performance in rechargeable batteries. Here we show that such Na(+)/vacan...

interaction of floral pigments with metal ions can alter the final color of the petals. metal ions can affect stability of flowers final color by altering vacuolar ph and activity of enzymes involved in biosynthesis, destruction, accumulation and transition of pigments. in this study, contents of metal ions of petal tissue and their relationships with parameters of petal color analyzed and comp...

Finding a viable electrolyte for next-generation 5 V-class lithium-ion batteries is of primary importance. A long-standing obstacle has been metal-ion dissolution at high voltages. The LiPF6 salt in conventional electrolytes is chemically unstable, which accelerates transition metal dissolution of the electrode material, yet beneficially suppresses oxidative dissolution of the aluminium current...

2D nanomaterials, including graphene, transition metal oxide (TMO) nanosheets, transition metal dichalcogenide (TMD) nanosheets, etc., have offered an appealing and unprecedented opportunity for the development of high-performance electrode materials for lithium-ion batteries (LIBs). Although significant progress has been made on 2D nanomaterials for LIB applications in the recent years, some m...

Abstract Sodium‐ion batteries (SIBs), which are an alternative to lithium‐ion (LIBs), have attracted increasing attention due their low cost of Na resources and similar storage mechanism LIBs. Compared with anode materials electrolytes, the development cathode lags behind. Therefore, key improving specific energy promoting application SIBs is develop high‐performance sodium intercalation materi...

Lithium-ion batteries (LIBs) have been widely used in the field of portable electric devices because of their high energy density and long cycling life. To further improve the performance of LIBs, it is of great importance to develop new electrode materials. Various transition metal oxides (TMOs) have been extensively investigated as electrode materials for LIBs. According to the reaction mecha...

A few electrons per ion scenario for the B = 0 metal-insulator transition in two dimensions Abstract We argue on the basis of experimental numbers that the B = 0 metal-insulator transition in two dimensions, observed in Si-MOSFETs and in other two-dimensional systems, is likely to be due to a few strongly interacting electrons, which also interact strongly with the random positively ionized imp...

Metal ion homeostasis is a critical function of many integral and peripheral membrane proteins. The genome of the etiologic agent of syphilis, Treponema pallidum, is compact and devoid of many metabolic enzyme genes. Nevertheless, it harbors genes coding for homologs of several enzymes that typically require either iron or zinc. The product of the tp0971 gene of T. pallidum, designated Tp34, is...

Hydrogelation behavior of two amino-terpyridine ligands in the presence of divalent metal ions in water was studied in detail. The effect of ligand structure and different counter anions on the gel morphologies was also explored.