few novel cobalt(ii) and copper(ii) complexes [m(fmp)3]cl2, [m(fmp)(bpy)2]cl2,[m(fmp)(phen)2]cl2 and [m(fmp)(phen)(bpy)]cl2 (fmp = 3-furan-2-ylmethylene-pentane-2,4-dione, phen = 1,10-phenanthroline, bpy = 2,2'-bipyridine) have been synthesized andcharacterized by elemental analyses, molar conductance, magnetic susceptibility measurements,ir, electronic, epr, mass spectra and cyclic voltam...

A novel method of photoinduced synthesis of unsymmetrical diaryl selenides from triarylbismuthines and diaryl diselenides has been developed. Although the arylation reactions with triarylbismuthines are usually catalyzed by transition-metal complexes, the present arylation of diaryl diselenides with triarylbismuthines proceeds upon photoirradiation in the absence of transition-metal catalysts. ...

Transition metal complexes have emerged as promising candidates for applications in solid-state electroluminescent devices. These materials serve as multifunctional chromophores, into which electrons and holes can be injected, migrate and recombine to produce light emission. Their device characteristics are dominated by the presence of mobile ions that redistribute under an applied field and as...

1. Definition of inorganometallic vs. organometallic chemistry 2. Inorganometallic Compounds Containing Transition Metal (TM) – Main Group Metal (E) Bond – Synthesis, Structure and Reactivity 2.1. Inorganometallic Complexes of TM with Group 13 Elements 2.1.1. Inorganometallic Complexes of TM with Boron 2.1.2. Inorganometallic Complexes of TM with Heavier Elements of Group 13 2.2. Inorganometall...

A series of dissymmetric dinuclear complexes were synthesized, as dual site catalysts in ethylene polymerization, by coupling the allylated a-diimine complexes of the metals Ti, Zr, V, Ni and Pd with the ansa-zirconocene complex [C5H4-SiH(Me)-C5H4]ZrCl2 possessing a hydride silane moiety. The different stages of syntheses included the formation of bis(cyclopentadienide)methyl silane which was u...

Abstract New N2O2 type Schiff base has been designed and synthesized by condensing 2,4 dihydroxy benzaldehyde and α-naphthylamine in ethanol. Solid metal complexes of the schiff base with Cu(II), Ni(II) and Zn(II) metal ion were synthesized and characterized by elemental analysis, magnetic susceptibility, molar conductance, IR, UV-Vis and ‘H NMR spectral studies. The data shows that the c...

The tetra azophenylcalix[4]arene with ortho-ester group was applied for determination of transition metal ions using spectrophotometer. In this case, the derivatives with ortho-ester group turned out the complexing formation selectively with transition metal ions over alkali, alkaline earth metal ions. From those, this study used the molecular mechanic method MM+ and molecular dynamic simulatio...

We have analyzed metal–ligand bonding in metallocenes using density functional theory (DFT) at the OPBE/TZP level. This level of theory was recently shown to be the only DFT method able to correctly predict the spin ground state of iron complexes, and similar accuracy for spin ground states is found here. We considered metallocenes along the first-row transition metals (Sc–Zn) extended with alk...

Chapter 21 Molecular modeling of transition metal complexes with nucleic acids and their constituents, 5y J. Kozelka Zinc complexes as targeting agents for nucleic acids, by E. Kimura and M. Shionoya Metallocene interactions with DNA and DNA-processing enzymes, by L. Y. Kuo, A. H. Liu and T. J. Marks .Evidence for a catalytic activity of. the DNA.double helix in the reaction 19etween DNA, platn...