Controlled self-assembly of polar aromatic silane leads to the formation of well-ordered lamellar structures. Graphite-like features are clearly visible with a scanning electron microscope (SEM). In addition, X-ray diffraction (XRD) patterns suggest a d spacing of 14.28 A along the z-axis and 4.42 A in the xy plane, which all agree with theoretical modeling. Constructing multistacks of silane m...

Nanocrystalline metals with average grain sizes of only a few nanometers have recently been observed to fail through the formation of shear bands. Here, we investigate this phenomenon in nanocrystalline Ni which has had its grain structure stabilized by doping with W, with a specific focus on understanding how strain localization drives evolution of the nanoscale grain structure. Shear banding ...

We describe stable intercalation compounds of the composition xN(2)·WO(3) (x = 0.034-0.039), formed by trapping N(2) in WO(3). The incorporation of N(2) significantly reduced the absorption threshold of WO(3); notably, 0.039N(2)·WO(3) anodes exhibited photocurrent under illumination at wavelengths ≤640 nm with a faradaic efficiency for O(2) evolution in 1.0 M HClO(4)(aq) of nearly unity. Spectr...

An electride has been synthesized that is stable to auto-decomposition at room temperature. The key was the theoretically directed synthesis of a per-aza analogue of cryptand[2.2.2] in which each of the linking arms contains a piperazine ring. This complexant was designed to provide strong complexation of Na+ via pre-organization of a "crypt" that contains eight nonreducible tertiary amine nitr...

Molecular dynamics simulations and density functional theory calculations have been used to demonstrate the possibility of preserving high spin states of the magnetic cores within Ni-based core-shell bimetallic nanoalloys over a wide range of temperatures. We show that, unlike the case of Ni-Al clusters, Ni-Ag clusters preserve high spin states (up to 8 μ(B) in case of Ni13Ag32 cluster) due to ...

Mesoporous gamma alumina fibres of high surface area, stable up to 1000 oC, were synthesized by bioreplica technique using sisal fibres as templates. Alumina formation during pyrolysis and calcination of fibres infiltrated with aluminium chloride solution has been studied, paying special attention to the interaction between the precursor and sisal fibres, using several experimental techniques s...

For the fabrication of practical E-O devices, critical material requirements, such as large E-O coefficients, high stability (thermal, chemical, photochemical, and mechanical), and low optical loss, need to be simultaneously optimized.1 In the past decade, a large number of highly active nonlinear optical (NLO) chromophores have been synthesized, and some of these exhibit very large macroscopic...

The electrical properties and thermal stability of ZrB2 Schottky contacts deposited on n-type GaN have been studied. As-deposited contacts had a barrier height of 0.80 eV, which decreased to 0.7 eV after annealing at 300 °C, and to 0.6 eV after additional annealing at 400 °C in nitrogen for 20 min. However, the barrier height remained at about 0.6 eV even when the diodes were annealed at 600 °C...

A new model for cooling flows in X-ray clusters, capable of naturally explaining salient features observed, is proposed. The only requirement is that a significant relativistic component, in the form of cosmic rays (CR), be present in the intra-cluster medium and significantly frozen to the thermal gas. Such an addition qualitatively alters the conventional isobaric thermal instability criterio...

Crop residues or mulches affect soil temperature influencing plant growth and related processes in the soil. A hot/cold plate combination was used to quantify heat transfer through several common dry test mulch materials (rubber chips, pine straw, wheat straw) and identify and quantify heat transfer mechanisms with the goal of modeling apparent thermal conductivity of the mulch. Mulch material ...