a facile and efficient one-pot three-step process for the synthesis of 5-acetyl-2-imino-4-methylthiazoles via the cyclocondensation of 3-thiocyanatoacetylacetone with various hydrazine or hydrazide derivatives in etoh has been developed. 3-thiocyanatoacetylacetone itself has been synthesized as the intermediate from substitution reaction of thiocyanate with 3-chloroacetylacetone. better results...

0

B. Synthetic procedures S2 B1. Synthesis of known compounds S2 B2. Synthesis of novel compounds S2 Fully deprotected Ni pyridyl porphyrin dimer NiP2 S2 Phenylacetylene Zn porphyrin tetramer PhC2-ZnP4 S3 Phenylacetylene Ni porphyrin tetramer PhC2-NiP4 S4 Phenylacetylene Ni porphyrin hexamer PhC2-NiP6 S5 Fully THS protected Zn porphyrin heptamer THS-ZnP7, octamer THS-ZnP8 and dodecamer THS-ZnP12 ...

purpose: compaison of excyclotorsion induced by horizontal transposition of vertical rectus muscles versus vertical transposition of horizontal rectus muscles in rabbit eyes. methods: in this exprimental study, group 1 underwent full tendon nasal transposition of the superior rectus and full tendon temporal transposition of the inferior rectus (10 adult rabbits); group 2 underwent superior tran...

aortoenteric fistula is a rare but significant clinical entity associated with high morbidity and mortality if remain untreated. clinical presentation and imaging findings may be subtle and prompt diagnosis can be difficult. herein, we present a patient who initially presented with abdominal pain and computed tomography showed an aortic aneurysm compressing duodenum without any air bubbles. one...

nowadays, due to recent developments and researches in dental science, it is possible to preserve and restore previously extracted cases such as teeth with extensive caries, fractured or less appropriate cases for crown coverage as well as teeth with external perforation caused by restorative pins. in order to restore the teeth with preservation of periodontium, we should know thoroughly physio...