We have demonstrated a NH3, NO2 and water vapour sensor based on poly(m-aminobenzene sulfonic acid) functionalized single-walled carbon nanotube (SWNT–PABS) networks. The SWNT–PABS based sensors were fabricated by simple dispersion of SWNT–PABS on top of pre-fabricated gold electrodes. SWNT–PABS sensors showed excellent sensitivity with ppbv level detection limits (i.e., 100 ppbv for NH3 and 20...

Transient grating measurements affirm the excitonic model for single-walled carbon nanotubes (SWNT) by identifying the dark exciton (D) as the population relaxation bottleneck in semiconducting-SWNT (S-SWNT). The data allow the reconstruction of the kinetics of excitonic cascade and cooling, from band continuum to vibrational cooling in the ground electronic state. In S-SWNT, the intraband rela...

A new poly(N-vinylcarbazole)-covalently grafted single-wall carbon nanotube (SWNT-PVK) hybrid material was synthesized by an in situ anionic polymerization reaction of N-vinylcarbazole and the negatively charged SWNTs. Incorporation of the PVK moieties onto the SWNTs' surface considerably improves the solubility and processability of SWNTs. At the same level of linear transmission, the SWNT-PVK...

Single-walled carbon nanotube ~SWNT! probe microscopy tips were grown by a surface growth chemical vapor deposition method. Tips consisting of individual SWNTs ~1.5–4 nm in diameter! and SWNT bundles ~4–12 nm in diameter! have been prepared by design through variations in the catalyst and growth conditions. In addition to high-resolution imaging, these tips have been used to fabricate SWNT nano...

Carbon nanotubes are archetypical one dimensional systems, with peculiar anisotropic electronic properties. Only recently μm thick films of vertically aligned SWNT became available. The vertical alignment of the nanotube mats allows the realization of scattering geometries promoting specific dipole transitions parallel and normal to the axis of the SWNT. We find well expressed mosaic spreads fo...

Metallic copper, which is normally considered as a contaminant in the growth of single-walled carbon nanotubes (SWNTs), was found to be an efficient catalyst to grow SWNTs under suitable conditions. It showed very high catalytic activity for the growth of both random SWNT networks and horizontally aligned SWNT arrays. Especially, high-quality SWNT arrays were obtained when monodispersed copper ...

In this study, a technique has been proposed for developing constitutive models for polymer composite systems reinforced with single-walled carbon nanotubes (SWNT) with various orientations with respect to the bulkmaterial coordinates. A nanotube, the local polymer adjacent to the nanotube, and the nanotube/polymer interface have been modeled as an equivalent-continuum fiber by using an equival...

The vibrational density of states of single-wall carbon nanotubes (SWNT) was obtained from inelastic neutron scattering data from 0 to 225 meV. The spectrum is similar to that of graphite above 40 meV, while intratube features are clearly observed at 22 and 36 meV. An unusual energy dependence below 10 meV is assigned to contributions from intertube modes in the 2D triangular lattice of SWNT bu...

The electrical transport and NH3 sensing properties of randomly oriented and aligned SWNT networks were presented and discussed. The results indicate that aligned SWNT-FETs have better FET characteristics due to the reduced number of interconnected nodes. This was particularly true as the resistance of the devices increased. Gated electrical breakdown was implemented to selectively remove metal...