In this study, a triblock copolymer, poly(styrene-isobutylene-styrene), was sulfonated to eight different levels ranging from 0.36 to 2.04 mequiv./g (13 to 82 mol% of styrene; styrene is 19 mol% of the unsulfonated block copolymer). These sulfonated polymers were characterized with elemental analysis and infrared spectroscopy to confirm sulfonation and determine accurate sulfonation levels. Inf...

Porous carbon/cobalt (C/Co) composite nanofibers with diameters of 200-300 nm were prepared by electrospinning and subsequent carbonization processes. Two polymer solutions of polyacrylonitrile (PAN), polyvinyl pyrrolidone (PVP), and Co (CH3COOH) 2 (Co (OAc) 2) were used as C/Co composite nanofiber precursors. The study revealed that C/Co composite nanofibers were successfully prepared and coba...

The purpose of this work is to develop a one-dimensional mathematical model for predicting the cell performance of a direct formic acid fuel cell and compare this with experimental results. The predicted model can be applied to direct formic acid fuel cells operated with different formic acid concentrations, temperatures, and with various electrolytes. Tafel kinetics at the electrodes, thermody...

Herein, using Isoreticular Zeolitic Imidazolate Frameworks (IRZIFs) as template, we report the synthesis, morphology and gas adsorption properties of porous carbon synthesized by nanocasting method at 1000 C, where furfuryl alcohol (FA) has been used as a carbon source. Using IRZIFs with variable porosity as templates, we could achieve the control over carbon porosity, H2 and CO2 uptake. The r...

The Dobroe deposit with 10 t gold reserves is one of the mines located within Yenisei Ridge Orogenic Belt. ore-forming conditions orogenic deposits are have recently been widely discussed. A comprehensive study fluid inclusions revealed that was formed by water–carbon dioxide and carbon dioxide–hydrocarbon fluids a temperature range 180 to 360 °C, pressure 0.8 1.3 kbar, salinity 1.5 15.0 wt.% (...

An efficient nanomedical platform that can combine two-photon cell imaging, near infrared (NIR) light and pH dual responsive drug delivery, and photothermal treatment was successfully developed based on fluorescent porous carbon-nanocapsules (FPC-NCs, size ∼100 nm) with carbon dots (CDs) embedded in the shell. The stable, excitation wavelength (λex)-tunable and upconverted fluorescence from the...

A new in situ Scanning Electron Microscope-Focused Ion Beam-based method to study porous carbon electrodes involving Pt filling of pores from gaseous precursors has been demonstrated to show drastically improved image contrast between the carbon and porous phases when compared with the Si-resin vacuum-impregnation method. Whereas, the latter method offered up to 20% contrast, the new method off...

In this work the synthesis of polyaniline/chitosan/functionalized single- walled carbon nanotube nanocomposite is carried out. For this purpose single -walled carbon nanotubes were reacted with thionyl chloride to change the hydroxyl to acyl chloride groups for improving the react ability. In other step, aniline monomers and chitosan were polymerized in the presence of Iron (III) chloride to sy...

Carbon-supported Pt catalysts have been widely employed as electrocatalysts for energy storage/conversion applications, but have encountered challenging instability issues. In this work, we investigated the degradation behaviors of pore-confined and surface-located Pt nanocatalysts, employing hollow porous carbon spheres with precisely controlled structure as catalyst supports. It is found that...

Electrospinning offers a powerful route for building one-dimensional (1D) micro/nanostructures, but a common requirement for toxic or corrosive organic solvents during the preparation of precursor solution has limited their large scale synthesis and broad applications. Here we report a facile and low-cost way to prepare 1D porous carbon microfibers by using an electrospun fiber-like natural pro...