نتایج جستجو برای: state reaction

تعداد نتایج: 1240671  

2002
Steven G. Boxer Christopher E. D. Chidsey Mark G. Roelofs

Magnetic Field Effects Prior to 1970 there were several reports of the effects of magnetic fields on chemical reactions, though there was much rebuttal and retraction in this early literature (1-3). Since 1970, the number of reproducible examples has grown rapidly. Most contemporary theories explaining these effects stem from the development of the radical pair theory of Chemically Induced Dyna...

Journal: :international journal of mathematical modelling and computations 0
deepti seth

a simple mathematical model of steady state  oxygen distribution subject to diffusive transport and non- linear uptake in a retinal cylinder has been developed. the approximate analytical solution to a reaction- diffusion equation are obtained by using series expansions. the computational results for the scaled variables are presented through graphs. the effect of the important parameters (1) d...

2012
Izumi Iwakura Atsushi Yabushita Jun Liu Kotaro Okamura Takayoshi Kobayashi

Allyl phenyl ether has an absorption band in the ultraviolet region (l o 400 nm); therefore, irradiation with few-optical-cycle ultraviolet pulses (l = 360–440 nm) causes a transition to the ultraviolet band, which leads to an electronic state and a photo-Claisen rearrangement (radical reaction) in the electronic excited state. However, the reaction scheme of allyl phenyl ether under irradiatio...

Journal: :Physical chemistry chemical physics : PCCP 2012
Izumi Iwakura Atsushi Yabushita Jun Liu Kotaro Okamura Takayoshi Kobayashi

Allyl phenyl ether has an absorption band in the ultraviolet region (λ < 400 nm); therefore, irradiation with few-optical-cycle ultraviolet pulses (λ = 360-440 nm) causes a transition to the ultraviolet band, which leads to an electronic state and a photo-Claisen rearrangement (radical reaction) in the electronic excited state. However, the reaction scheme of allyl phenyl ether under irradiatio...

پایان نامه :وزارت علوم، تحقیقات و فناوری - دانشگاه رازی - دانشکده علوم 1390

abstract in first part of this project, the use of a new and biguanid-like catalyst supported on silica as a recyclable catalyst provides a new route for the synthesis of a variety of arylalkylidene rhodanine derivatives through knoevenagle reaction in at present of solvent at room temperature. rhodanine derivatives and especially arylalkylidene rhodanines have proven to be attractive compound...

Journal: :The Journal of organic chemistry 2004
Wei Quan Tian Yan Alexander Wang

The Staudinger reactions of substituted phosphanes and azides have been investigated by using density functional theory. Four different initial reaction mechanisms have been found. All systems studied go through a cis-transition state rather than a trans-transition state or a one-step transition state. The one-step pathway of the phosphorus atom attacking the substituted nitrogen atom is always...

پایان نامه :وزارت علوم، تحقیقات و فناوری - دانشگاه سیستان و بلوچستان - دانشکده علوم پایه 1387

در این تحقیق سینتیک و مکانیزم واکنش بین تری فنیل فسفین و دی متیل استیلن دی کربوکسیلات در حضور ترکیبات nh-اسید ایمیدازول، 2-متیل ایمیدازول و 4- متیل ایمیدازول به شیوه محاسبات مکانیک کوانتومی بررسی شد. تمامی ساختارهای شرکت کننده در واکنش با روشهای hf و b3lyp و به ترتیب در سطوح 6-31g (d,p) , 6-311++g(d,p) بهینه شدند. بعلاوه در روش hf برای ساختارهای حاوی فسفر از تابع اضافی 6-31+g(3df,3pd) و در روش ...

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