The distribution of Cd in the presence of phthalic acid (H2Lp), ferrihydrite and bacteria (Comamonas spp.) was investigated in biologically active systems involving H2Lp biodegradation. Tests showed that Cd sorption onto bacteria, ferrihydrite and bacteria–ferrihydrite mixture increased with pH in all systems, irrespective of H2Lp degradation or not. The use of bacterial growth medium, Bushnell...

Sorption of crude oil by mineral surfaces may a€ect its ̄ow and recovery in porous media. Here, crude oil sorption from a toluene±heptane phase onto quartz and silica gel has been investigated both in the presence and absence of an aqueous phase, as a function of time, oil-to-sorbent ratio, pH, and wetting sequence. Steady-state is attained in roughly 24 h, with sorption following Freundlich is...

nanoparticles of manganese-dioxide synthesized by mechano-chemical reaction were used foras(iii) and as(v) sorption from water environment. the influence of a milling time of manganese-dioxide on sorption was examined with batch procedure. sorption as a function of contact time was investigated. kinetic of sorption, for both as(iii) and as(v), was fast. the equilibrium condition for milled sorb...

Rates of biodegradation of sorbed chemicals are usually lower in soil than in aqueous systems, in part because sorption reduces the availability of the chemical to microorganisms. Biodegradation, sorption, and diffusion occur simultaneously and are tightly coupled. In soil, the rate of biodegradation is a function of a chemical's diffusion coefficient, sorption partition coefficient, the distan...

The organic-inorganic hybrid material of polyaniline/titanium(IV) (PANI/Ti(HPO4)2) was synthesized by an oxidative polymerization reaction. The PANI/Ti(HPO4)2 was applied to remove Re(VII). The size of Ti(HPO4)2 nanoplates has no obvious effect on the sorption capacity. The effects of various environmental factors (such as pH, extra anions (NO3(-) and MO4(2-)) and temperature) on Re(VII) sorpti...

the aim of this study was to investigate the congo red sorption on soil from the region of iasi (ne of romania). the effects of contact time, temperature, sorbent dose and initial dye concentration on soi sorption were investigated. the results show that the amount adsorbed of congo red on soil increase with increasing dye concentration, temperature and contact time. the experimental data were ...

abstract siderophores are of important factors influencing bioavailability and fate of heavy metals in the arid and semi-arid soils. they are low molecular weight organic ligands excreted by aerobic soil microorganisms and some plants roots to acquire fe. siderophores may also complex other metals such as pb .the main objective of this study was to investigate the effects of dfob-siderophore on...

One- and two-dimensional nuclear magnetic resonance (NMR) experiments were performed on Agave americana cutan and tomato cutin to examine the interactions between a hydrophobic pollutant, pyrene, and cuticular material. Variable-temperature NMR experiments show that cutan, an acid- and base-resistant cuticular biopolymer, undergoes the characteristic melting behavior of "polyethylene-like" crys...

factors that affect stability. The interaction of pharmaceutical solids with water can affect their chemical stability as well as their physical and mechanical properties. The influence of moisture on solid-state stability has therefore been extensively documented. It is important now to understand and to anticipate the behaviour of a product exposed to a variety of environmental conditions (e....