Molecular dynamics simulation is performed on the buckling behavior of single and multi-walled carbon nanotubes under axial compression. Brenner’s ‘second generation’ empirical potential is used to describe the many-body short range interatomic interactions for singlewalled carbon nanotubes, while the Lennard Jones 12-6 model for van der Waals potential is added for multi-walled carbon nanotube...

Carbon nanotubes and graphene are extra-ordinal material with remarkable electrical, optical, mechanical and thermal properties. Films of vertically aligned (VA-) SWNTs and horizontally aligned (HA-) SWNTs are synthesized on quartz and crystal quartz substrates, respectively. These aligned film should inherit the remarkable properties of SWNTs. The recent progress in growth control and characte...

We demonstrate the efficient chemical vapor deposition synthesis of single-walled carbon nanotubes where the activity and lifetime of the catalysts are enhanced by water. Water-stimulated enhanced catalytic activity results in massive growth of superdense and vertically aligned nanotube forests with heights up to 2.5 millimeters that can be easily separated from the catalysts, providing nanotub...

Stable aqueous SWNT dispersion up to 92% was achieved using amino acid based amphiphiles through a structure-property investigation. The nanohybrids showed remarkable serum stability and biocompatibility to mammalian cells.

We show that single-walled carbon nanotube (SWNT) bundles emit visible fluorescence in the presence of noble metal nanoparticles and nanorods in the solid state. Conductivity measurements with metallic nanotubes, isolated from pristine SWNTs, show that they become semiconducting in the presence of the metal nanoparticles. Nanoparticle binding increases the defects in the nanotube structures whi...

We report the capacitive spring softening effect observed in single-walled carbon nanotube (SWNT) nanoelectromechanical (NEM) resonators. The nanotube resonators adopt a dual-gate configuration with both bottom-gate and end-gate capable of tuning the resonance frequency through capacitive coupling. Interestingly, downward resonance frequency shifting is observed with increasing end-gate voltage...

We report measurements on ropes of single-walled carbon nanotubes (SWNT) in low-resistance contact to nonsuperconducting (normal) metallic pads, at low voltage and at temperatures down to 70 mK. In one sample, we find a 2 orders of magnitude resistance drop below 0.55 K, which is destroyed by a magnetic field of the order of 1 T, or by a dc current greater than 2.5 microA. These features strong...

Direct conversion from heat to electricity is one of the important technologies for a sustainable society since large quantities of energy are wasted as heat. We report the development of a single-walled carbon nanotube (SWNT)-based high conversion efficiency, air-stable and flexible thermoelectric material. We prepared cobaltocene-encapsulated SWNTs (denoted CoCp2@SWNTs) and revealed that the ...

Photoluminescence (PL) identifies spectroscopic signatures of intertube transfer of optically pumped carriers in single-walled carbon nanotube (SWNT) ensembles. Resonant photoexcitation of large band gap SWNTs produces strong PL from smaller band gap SWNTs. Magnetic alignment measurements associate the energy-transfer PL peaks with the formation of SWNT bundles, suggesting that efficient coupli...

Motivated by recent experiments, we investigate how NO3-SWNT interactions become energetically favorable with varying oxidation state of a single-walled carbon nanotube (SWNT) using first-principles calculations. Chemisorption becomes less endothermic with respect to physisorption when the SWNT oxidation state is elevated. Importantly, the dissociative incorporation of an oxygen atom into the S...