Understanding working principles and thermodynamics behind phase separations, which have significant influences on condensed molecular structures their performances, can inspire to design fabricate anomalously desirably mechanoresponsive hydrogels. However, a combination of techniques from physicochemistry mechanics has yet been established for the separation in In this study, thermodynamic mod...

Measurements revealing anomalously large frictional drag at the transition between the weakly and strongly coupled regimes of a bilayer two-dimensional electron system at total Landau level filling factor nu(T)=1 are reported. This result suggests the existence of fluctuations, either static or dynamic, near the phase boundary separating the quantized Hall state at small layer separations from ...

The business-cycle behavior of a matching model with endogenous separations is studied in this paper. We show that whether aggregate productivity shocks have a larger effect on the vacancy–unemployment ratio than in a model with exogenous separations depends on whether worker productivity stochastically increases with tenure. The difference in the response is quantitatively small, however. We a...

Separations of 15 pM rhodamine 6G and 30 pM rhodamine B performed in a micromachined electrophoresis channel were detected by counting fluorescence bursts from individual molecules. The migration times, peak widths, and analyte concentrations were estimated from the number and the migration time distribution of the detected molecules. Concentration detection limits estimated at >99% confidence ...

The work presented herein evaluates silicon nano-pillar arrays for use in planar chromatography. Electron beam lithography and metal thermal dewetting protocols were used to create nano-thin layer chromatography platforms. With these fabrication methods we are able to reduce the size of the characteristic features in a separation medium below that used in ultra-thin layer chromatography; i.e. p...

Ultrafast reversed-phase high-performance liquid chromatographic (HPLC) separations are often needed for analyses related to combinatorial chemistry, studies in liquid chromatography-mass spectrometry, and other applications in which very rapid sample turnaround is paramount. Unfortunately, no consensus exists regarding the best column technology for optimally performing the desired rapid separ...

New materials capable of separating mixtures of saturated, unsaturated, and aromatic hydrocarbons can enable more efficient industrial processes and cleaner energy. Outstanding challenges in hydrocarbon separations stem from the similar structures, properties, and reactivities of the molecules comprising many of these mixtures. With high surface areas, tunable pore geometries, and adjustable su...

An Agilent ZORBAX sub-2 μm Rapid Resolution High Definition (RRHD) 300SB-C8 reversed-phase column was used under optimized chromatographic conditions for delivering highly resolved ultra fast separations of reduced and alkylated monoclonal antibodies. The StableBond C8 phase and RRHD column technology, in combination with robust gradient elution conditions enabled efficient, fast, and effective...

A. Introduction B. Optical and Spectrophotometric Detectors 1. Differential refractometry 2. Ultraviolet spectrophotometry 3. Fluorescence detection 4. Infrared spectrophotometric detectors 5. Spectrophotometric detection with post-column chemical reaction C. Some Miscellaneous Detection Systems 1. The mass spectrometer as an HPLC detector 2. Radioactivity detectors 3. Density, electrochemical ...