Two-phase liquid system IA(w)|IX(o) comprising the interface between the aqueous solution (w) of uni-univalent electrolyte IA and an organic solvent solution (o) of a uni-univalent electrolyte IX with the common cation I(+) is considered as a simple model of a liquid-membrane ion-selective electrode (ISE). Taking into account the electroneutrality and mass balance conditions, the equilibrium Ga...

A poly(3,4-ethylenedioxythiophene)-b-poly(ethylene glycol) (PEDOT-b-PEG) block copolymer doped with perchlorate on FTO shows excellent optical and interfacial performance as a counter electrode (CE), such as low charge transfer resistance and low reflectivity for polymer electrolyte-based solid-state dye-sensitized solar cells (DSCs), resulting in 8.45% energy conversion efficiency, greater tha...

The stability constants of Cu'(l1) glycine complexes in 0.7 M NaC104 and 0.7M NaN03 media were evaluated using Cu ( 1 1 ) ion selective electrode. The stability constant data are consistent with earlier reports of other metal ion complexes of glycine. The distribution level of Cu ( 1 1 ) glycine complexes in presence of other complexing ligands of marine environment has also been numerically ev...

Individual laser-cooled 24Mg+ ions are confined in a linear Paul trap with a novel geometry where gold electrodes are located in a single plane and the ions are trapped 40 microm above this plane. The relatively simple trap design and fabrication procedure are important for large-scale quantum information processing (QIP) using ions. Measured ion motional frequencies are compared to simulations...

Three novel phenyltelluroalkoxyl functionalized tweezer-like calix[4]arenes 6-8 and two monophenyltelluropropoxyl functionalized calix[4]arenes 10 (cone conformer) and 12 (partial cone conformer) were synthesized and characterized. They are good Ag(+)-selective ionophores in ion-selective electrodes evaluated by electromotive force measurements of polymer membrane electrodes. The tweezer-like i...

A technique for the selective measurement of diffusive gradients in thin-films (DGT) for free Cu2+ ions was developed using a 0.030 M solution of polyvinyl alcohol (PVA) as the liquid binding phase with the liquid-type DGT devices (PVA DGT). The PVA DGT had a substantial binding capacity at pH 5.6 - 8.6 and concentrations of competitive Na+ up to 0.7 M. The measurements of PVA DGT and cupric io...

An integrated computer system consisting of an expandable ionanalyzer and a PC has been used to automate concentration measurements with ion-selective electrodes (ISEs). The ionanalyzer determines ionic concentrations using a reference electrode coupled with an ISE. The measurements and calibrations are carried out in a thermostated sample changer equipped with a flow cell. The data obtained by...

We use ab initio density functional calculations to study the stability, elastic properties and electronic structure of sp(2) carbon minimal surfaces with negative Gaussian curvature, called schwarzites. We focus on two systems with cubic unit cells containing 152 and 200 carbon atoms, which are metallic and very rigid. The porous schwarzite structure allows for efficient and reversible doping ...

Printing techniques have been extensively used in the fabrication of organic electronic devices, such as light-emitting diodes and display backplanes. These techniques, in particular inkjet printing, are being employed for the localized dispensing of solutions containing biological molecules and cells, leading to the fabrication of bio-functional microarrays and biosensors. Here, we report the ...

The potential response of an ion-exchanger type PVC ion-selective electrode (ISE) for a drug ion, desipramine(+) (DES(+)), was analyzed by a mixed-potential (MP) theory proposed previously. The transfer of DES(+) and its analogous ions, imipramine(+) (IMP(+)) and neostigmine(+) (NEO(+)), at a micro Ο-nitrophenyl octyl ether/water interface was studied by ion-transfer voltammetry; also, the stan...