dissolution pressure and nozzle temperature effects on particle size and distribution were investigated for ress (rapid expansion of supercritical solution) process. supercritical co2 was used as solvent and ibuprofen was applied as the model component in all runs. the resulting ibuprofen nano-particles (about 50 nm in optimized runs) were analyzed by sem and laser diffraction particle size ana...

The optical properties of two Re(CO)3(bpy)Cl complexes in which the bpy is substituted with donor (triphenylamine, TPA, ReTPA2) as well both (TPA) and acceptor (benzothiadiazole, BTD, ReTPA-BTD) groups are presented. For ReTPA2 absorption spectra show intense intraligand charge-transfer (ILCT) bands at 460 nm small solvatochromic behavior; for ReTPA-BTD ILCT transitions weaker. These assigned T...

Esterification of starch was carried out to expand the usefulness of starch for a myriad of industrial applications. Lipase B from Candida antarctica, immobilized on macroporous acrylic resin (Novozym 435), was used for starch esterification in two reaction systems: micro-solvent system and solvent-free system. The esterification of corn starch with palmitic acid in the solvent-free system and ...

A Nonlinear Mixed Integer Programming approach is presented to select the number of membrane modules required in the extraction and stripping sectors of a Non Dispersive Solvent Extraction Plant for effluent treatment and metal recovery. The differential equations that model each membrane module are discretized using orthogonal collocation on finite elements leading to an algebraic system of eq...

In metabolic engineering of prokaryotes, combinatorial approaches have developed recently that induce random genetic perturbations to achieve a desired cell phenotype. A screening strategy follows the randomized genetic manipulations to select strain(s) with the more optimal phenotype of interest. This screening strategy is often divided into two categories: (i) a growth competition assay and (...