The dynamics of retained and deactivating species in a SAPO-18 catalyst during the methanol-to-olefins reaction have been followed using combination ex-situ in-situ techniques differential integral reactors.The were analyzed extraction, FTIR UV-vis spectroscopies combined with online product analysis (gas chromatography mass spectrometry). composition extracted soluble was determined gas chroma...

SSZ-13 materials have been synthesized with varying amounts of Al to produce samples with different concentrations of Brønsted acid sites, and consequently, these SSZ-13 materials contain increasing numbers of paired Al heteroatoms with increasing Al content. These materials were then characterized and tested as catalysts for the methanol-toolefins (MTO) reaction at 400 °C and 100% methanol con...

The catalytic purification of automobile exhaust gases (CO, NOx and hydrocarbons) is one of the most practiced conversion processes used to lower the emissions and to reduce the air pollution. Nevertheless, the good performance of exhaust gas purification catalysts often requires the high consumption of noble metals such as platinum. Here we report that the Brønsted acid sites on the external s...

Abstract. SAPO-34 and ZnAPO-34 materials (Zn incorporated by isomorphic substitution in AlPO-34 material) were synthesized hydrothermal synthesis using triethylamine (TEA) as the structure directing agent (SDA). The presented both is to chabazite zeolite (CHA). However, they have different properties such textural (Z34 S34 a surface area of ​​485 603 m2/g, respectively), crystal sizes acid prop...