even purified enzyme preparations are often heterogeneous. for example, preparations of aspartate aminotransferase or cytochrome oxidase can consist of several different forms of the enzyme.  for this reason we consider how different the kinetics of the reactions catalysed by a mixture of forms of an enzyme must be to provide some indication of the characteristics of the species present.  based...

the density and viscosity values at t= (293.15 to 323.15) k for binary mixtures of nitromethane with 2-propanol, 2-butanol and 2-pentanol were measured over the entire composition range. from the experimental data, excess molar volumes, thermal expansion coefficients, excess thermal expansions, partial molar volumes at infinite dilution and deviations in viscosity were calculated. the results w...

Mannitol, a common pharmaceutical ingredient, exhibits complex polymorphism even in simple binary mannitol/water mixtures, with four crystalline forms observed. In this investigation, time/temperature-resolved synchrotron X-ray diffraction measurements are performed during freezing and thawing of mixtures. Mannitol crystallization depends strongly on the cooling rate is initiated cooling, if lo...

A general multi-scale framework for multi-component, multi-phase equilibrium flash calculations, which uses information at the molecular and bulk fluid length scales, is described. The multi-scale Gibbs–Helmholtz constrained (GHC) EOS approach of Lucia (2010) is extended to include the use of (1) coarse grained NTP Monte Carlo simulations to gather pure component internal energies of departure,...

The rule of mixtures (ROM) method is often used to estimate the tensile strength of fiber reinforced polymers (FRPs) reinforcing bars (rebars). Generally, the ROM method predicts the FRP rebars’ modulus of elasticity adequately but overestimates their tensile strength. This may result from defects occurred during manufacture that prevent the used materials from exhibiting a sound performance an...

This paper describes the use of Bernoulli mixture models for extracting boolean rules from data. Bernoulli mixtures identify high data density areas on the corners of a hypercube. One corner represents a conjunction of literals in a boolean clause and the set of all identified corners, of the hypercube, indicates disjuncts of clauses to form a rule. Further class labels can be used to select fe...

In this paper we present an iterative inversion (II) approach to blind source separation (BSS). It consists of a quasi-Newton method for the resolution of an estimating equation obtained from the implicit inversion of a robust estimate of the mixing system. The resulting learning rule includes several existing algorithms for BSS as particular cases giving them a novel and unified interpretation...

In recent years, we have studied information properties of various types of mixtures of probability distributions and introduced a new type, which includes previously known mixtures as special cases. These studies are disseminated in different fields: reliability engineering, econometrics, operations research, probability, the information theory, and data mining. This paper presents a holistic ...

using the evaporating method, the solubility of potassium nitrate was determined in various mixtures containing water and ethanol at 25°c. the results show that the solubility of kno3 decreases with increasing the mass percent of ethanol in the mixtures. this trend is along with decreasing the dielectric constant of water+ethanol mixtures. moreover, it can be concluded that the totqal solubilit...