Abstract The influence of fiber drawing on mechanical and vibrational properties RE-doped sol-gel silica is disclosed by a comparison bulk silica, before after the melting process, fibers. characterization carried out nanoindentation technique: hardness elastic modulus are found to be consistent with those Corning 7980 reference glass, related elasto-plastic behavior glassy material. Our result...

To analyze the regulation of gene rearrangement at the T cell receptor (TCR) alpha/delta locus during T cell development, we generated transgenic mice carrying a human TCR delta gene minilocus. We previously showed that the presence of the TCR delta enhancer (E delta) within the J delta 3-C delta intron was required to activate a specific step (V-D to J) of transgene rearrangement, and that rea...

We prove the existence of steady 2-dimensional flows, containing a bounded vortex, and approaching a uniform flow at infinity. The data prescribed is the rearrangement class of the vorticity field. The corresponding stream function satisfies a semilinear elliptic partial differential equation. The result is proved by maximizing the kinetic energy over all flows whose vorticity fields are rearra...

Nano silica-H2SO4 is an efficient and mild catalysis system for the regeneration of aldehyde from aldoximes. Ketoximes are converted to amides by Beckmann rearrangement in the presence of nano silica-H2SO4. The reactions are carried out in solvent-free conditions under microwave irradiation (600 W) within 50-120 sec in good yields.

Rearrangement reactions of cycloalkenyl phenol and naphthyl ethers and the acid-catalyzed cyclization of the resulting product were investigated. Claisen rearrangement afforded 2-substituted phenol and naphthol derivatives. Combined Claisen and Cope rearrangement resulted in the formation of 4-substituted phenol and naphthol derivatives. In the case of cycloocthylphenyl ether the consecutive Cl...

Rimonabant monohydrate can be dehydrated at 100 °C or above with complete loss of structural information; in this case the amorphous material can lead to nucleation and crystal growth. The water molecules can also be removed by a smooth process below Tg (78 °C) of the anhydrous phase. In that latter process there is a structural filiation between the mother phase and the daughter phase. The sol...