Biaryl compounds are versatile building blocks in the synthesis of natural products, pharmaceuticals, agricultural chemicals and π-conjugated organic materials. This review describes a recent progress for the biaryl cross-coupling reaction of heteroaromatic compounds using hypervalent iodine reagent. Our novel biaryl coupling reaction is a unique method for constructing various heteroaromatic b...

S(RN)1-type coupling adducts are readily prepared by the reaction between a-sulfonylesters or a-cyanosulfones and gem-dinitro compounds in ionic liquids. The reactions progress smoothly and recovered ionic liquids can be used for several iterations, as long as they are washed with water to remove alkali metallic salts. The reaction rate is slower than the corresponding S(RN)1 reaction in DMSO, ...

Oxidized l-glutathione was esterified to the tetra methyl ester using thionyl chloride in methanol solvent. Other alcohols were tested and the reaction progress was monitored via ESI-MS. This procedure proved to be compatible with other small peptides not containing serine and cysteine residues. In contrast to previously reported methods this procedure provided convenient access to esterified p...

the indexed iranian journals in isi and pubmed at the end of 2012 with known impact factor (if) were evaluated with regard to the number of articles published in 2010-2012, the number of citations by authors from inside and outside iran, their if as well as their ranking order among all other journals in their specialized categories. there were among 130 english journals, 21 indexed with known ...

This paper presents a simple solution to the problem of approximating the calculated curve of reaction progress to the measured curve which is usually disturbed by initial oscillation of auxiliary lactate dehydrogenase (LDH) reaction. The experiments leading to the determination of the apparent Km for phosphoenolpyruvate (PEP) and Vm were performed. For precise estimation of kinetic parameters ...

The befitting capping capabilities of AsO4(3-) provide a stable Cu2O nanocatalyst from a galvanic reaction between a Cu(II) precursor salt and As(0) nanoparticles. This stable Cu2O hydrosol appears to be a suitable catalyst for the one-electron transfer reversible redox reaction between Eosin Y and NaBH4. The progress of the reaction relates to three different kinetic stages. In the presence of...

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Although intensive efforts have been made and great progress has achieved relating to the electrocatalytic hydrogen evolution reaction (HER), an advanced synthesis strategy for efficient electrocatalyst is still most significant goal.

We present an original fluorescence imaging strategy to spatially probe the real-time progress of a quenching reaction diffusing throughout permeable 3D-microstructures whose geometry and topology are modulated by two-photon stereolithography.

Large-eddy simulation (LES) of a lifted flame in a vitiated co-flow has been performed using an unsteady flamelet/progress variable (UFPV) model. This model is an extension to the steady flamelet/progress variable approach, and describes the transient autoignition process of the lifted flame through the unsteady flamelet model. The particular advantage of this model is that it eliminates the fl...