نتایج جستجو برای: ray absorption spectroscopy
تعداد نتایج: 546748 فیلتر نتایج به سال:
An explanation of the relative intensity fluctuations observed in single-molecule Raman experiments is described utilizing both single-molecule tip-enhanced Raman spectroscopy and time-dependent density functional theory calculations. No correlation is observed in mode to mode intensity fluctuations indicating that the changes in mode intensities are completely independent. Theoretical calculat...
The first series of complexes of niobium(v) oxide trifluoride, [NbOF3(OPR3)2] (R = Me or Ph), [NbOF3(dppmO2)] (dppmO2 = Ph2P(O)CH2P(O)Ph2), [NbOF3(dmso)2], [NbOF3(tmeda)] (tmeda = Me2N(CH2)2NMe2) and [NbOF3(diimine)] (diimine = 2,2'-bipy, 1,10-phen) have been prepared, either by reaction of the corresponding complexes of NbF5 and hexamethyldisiloxane (HMDSO) in CH2Cl2-MeCN solution, or directly...
The magnetostrictive atomic strain in a pure Fe single crystal was measured by differential x-ray absorption spectroscopy. The obtained tetragonal magnetostriction constant, (3/2)λ100, was determined to be 45 ppm, consistent with the previously reported theoretical value calculated from a spin-orbit coupling theory. These results provide a foundation for understanding the origin of magnetostric...
We report measurements of the physical properties and electronic structure of the hexagonal compounds Yb2Ni12Pn7 (Pn = P, As) by measuring the electrical resistivity, magnetization, specific heat and partial fluorescence yield x-ray absorption spectroscopy (PFY-XAS). These demonstrate a crossover upon reducing the unit cell volume, from an intermediate valence state in Yb2Ni12As7 to a heavy-fer...
Figu (Seco edge detec emp We describe a non-photorealistic camera (‘NPR camera’) to robustly capture edge information in real scenes. New stylized images are synthesized by highlighting or de-emphasizing the detected edges.
Using x-ray absorption spectroscopy, we have studied the effect of pressure on femtometer-scale bond strain due to anisotropic magnetostriction in a thin FeCo film. At 7 GPa local magnetostrictive strain is found to be larger than at ambient, in agreement with spin-polarized ab initio electronic structure calculations, but contrary to the expected effect of compression on bond stiffness. The av...
Electronic structure of liquid water from polarization-dependent two-photon absorption spectroscopy.
Two-photon absorption (2PA) spectroscopy in the range from 7 to 10 eV provides new insight on the electronic structure of liquid water. Continuous 2PA spectra are obtained via the pump-probe technique, using broadband probe pulses to record the absorption at many wavelengths simultaneously. A preresonance enhancement of the absolute 2PA cross section is observed when the pump-photon energy incr...
Resonant (elastic) soft x-ray scattering (RSXS) offers a unique element, site and valence specific probe to study spatial modulations of charge, spin and orbital degrees of freedom in solids on the nanoscopic length scale. It is not only used to investigate single-crystalline materials. This method also enables one to examine electronic ordering phenomena in thin films and to zoom into electron...
Compositional, microstructural, and magnetic characterization of ZnO 30 Å /Mn x n multilayers prepared by sputtering is presented to study the observed ferromagnetism in the Mn-ZnO system. The nominal Mn layer thickness, x, is varied from 3 to 60 Å, while the number of bilayers, n, is increased to maintain the total amount of Mn constant. Microstructure information was deduced from x-ray reflec...
امـروزه بازیـافت فلـزات گروه پـلاتین (پلاتین، پالادیوم، رودیوم) از پسـاب های صنعـتی به دلیـل ارزش اقتـصادی بالا و کاربـرد فراوان این فـلزات در صنـایع مختـلف از جمـله صنـایع نفـت و گـاز و مجتـمع های پتـروشیـمی (به عنوان کاتالیـست یا پایه کاتالیـست)، سـاخت قطعـات پزشکی، صنـعت الکتـرونیک، جواهرسـازی مورد استفاده قرار می گیرد. روشهای متـعددی برای بازیافت فلز پـالادیـوم و سـایر فلـزات گـرانبها از ک...
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