The previously reported monochelate iron complex with κ(3) SNS thioamide pincer ligand, 2,6-bis(N-2,6-bis(diphenylmethyl)-4-isopropylphenyliminothiolate)pyridine (L(DPM)), [Fe(THF)2(κ(3)-L(DPM))], gave novel complexes, [Fe(NHC)(κ(3)-L(DPM))] and [Fe(NO)2(κ(3)-L(DPM))], by substitution reactions with N-heterocyclic carbene (NHC) and NO molecules, respectively. The X-ray crystal structure of the ...

Pacaud and Uriel described an enzyme from Escherichia coli ("protease I") that hydrolyzes acetyl phenylalanine naphthyl ester (APNE). We examined the possible involvement of this enzyme in intracellular protein degradation, its subcellular distribution, and its proteolytic activity. Although the APNE-hydrolyzing activity is localized primarily in the periplasm, proteolytic activity against case...

ABSTRACT Noria derivatives containing protective groups such as t-BOC group, t-butyl ester group (t-BAc), adamantyl group (Ad) were synthesized and evaluated as alkaline developable positive-type EBand EUV-resists. As the result, it was cleared that Noria-t-BOC and Noria-t-BAc showed 50 nm and 70 nm resolutions as EB-resists, respectively. Noria-Ad also showed clear line and space pattern with ...

Seven new azalomycin F analogs (1-7) were isolated from the broth of mangrove Streptomyces sp. 211726, and respectively identified as 25-malonyl demalonylazalomycin F5a monoester (1), 23-valine demalonylazalomycin F5a ester (2), 23-(6-methyl)heptanoic acid demalonylazalomycins F3a ester (3), F4a ester (4) and F5a ester (5), 23-(9-methyl)decanoic acid demalonylazalomycin F4a ester (6) and 23-(10...

In contrast to fi-glutamine and @glutamylhydroxamic acid, fl-glutamic acid does not possess an asymmetric carbon atom, but has, according to the nomenclature of Schwartz and Carter (2), a meso carbon atom. The present experiments were designed to determine whether glutamine synthetase distinguishes between the carboxyl groups of P-glutamic acid. It is noteworthy in this connection that the enzy...

diesel fuel has a limited resource and concerns over environmental pollution areleading to the use of ‘bio-origin fuels’ as they are renewable and environmentally benign. jatrophamethyl ester, an esterified biofuel, has an excellent cetane number and a reasonable calorific value.it closely resembles the behaviour of diesel. however, being a fuel of different origin, the standarddesign limits of...

Laboratory studies were conducted using C-aminocyclopyrachlor (DPX-MAT28) and its C-methyl ester formulation (DPX-KJM44) to (1) determine the adjuvants’ effects on absorption, (2) compare the absorption and translocation of aminocyclopyrachlor free acid with the methyl ester, and (3) determine the rate at which aminocyclopyrachlor-methyl ester is metabolized to the free acid in Canada thistle. ...

The extraction of yacon [Smallanthus sonchifolius (Poepp. and Endl.) H. Robinson; Asteraceae] leaves and chromatographic separation yielded two new antibacterial melampolide-type sesquiterpene lactones, 8beta-tigloyloxymelampolid-14-oic acid methyl ester and 8beta-methacryloyloxymelampolid-14-oic acid methyl ester, as well as the four known melampolides, sonchifolin, uvedalin, enhydrin and fluc...

Alkylation of beta-amino ester enolates proceeds with high diastereoselectivity. Single crystal, powder, and solution X-ray diffraction studies of the enolate show that the racemic enolate forms prismatic hexamers. 6Li NMR spectroscopic studies on partially racemic enolates reveal complex mixtures of homo- and heterochiral hexamers. An implicit fit of the aggregate populations to the Boltzmann ...