In classical thermodynamic, maximum power obtained from system (or minimum power supplied to system) defined as availability (exergy), but availability term is only used for reversible systems. In reality, there is no reversible system, all systems are irreversible, because reversible cycles doesn’t include constrains like time or size and they operates in quasi-equilibrium state. Purpose of th...

New symmetrical acyclic binuclear copper (II) complexes [CuL](ClO4)2 1 and 2 were synthesized by template method, from bicompartmental ligand 2,6-bis((E)-(2-(2aminoethylamino)ethylimino)methyl)-4-methylphenol (L) and 2-((7E)-(2-((Z)-2-((naphthalen-1-yl) methyleneamino)ethylamino)ethylimino)methyl)-6-((9E)-(2-((Z)-2-((naphthalen-1-yl)methyleneamino) ethylamino)ethylimino) methyl)-4-methylphenol ...

We report a kinetic and mechanistic study into the one-electron reduction of the archetypal Lewis acid tris(pentafluorophenyl)borane, B(C(6)F(5))(3), in dichloromethane and 1,2-difluorobenzene. Electrochemical experiments, combined with digital simulations, DFT computational studies and multinuclear NMR analysis allow us to obtain thermodynamic, kinetic and mechanistic information relating to t...

An N(4) tetradentate [1 + 1] Schiff base metal free macrocycle HL was prepared, by 1 : 1 condensation of 2,2'-iminobisbenzaldehyde (1) and diethylenetriamine, and characterised. Seven mononuclear complexes, [Zn(II)L(py)](BF(4)) (2), [Cu(II)L](BF(4))]·H(2)O (3), [Ni(II)L](BF(4))·H(2)O (4), [Co(II)L](BF(4))]·H(2)O (5), Fe(III)L(BF(4))(2)·2H(2)O·MeCN (6), [Co(III)L(NCS)(2)]·0.3py (7) and [Fe(III)L...

Background: The SubBytes and InvSubBytes transformations of Advanced Encryption Standard (AES) algorithm are conventionally implemented by using either look-up tables or combinational logic circuits. Both implementations are susceptible to power analysis attacks as they consume substantial amount of power during their normal operation. Objective: To overcome the power analysis attacks in SubByt...

Macrocycles and p-benzoquinones (p-BQ) have been generally connected as potential co-synergist redox models in aerobic oxidation. To get insight for the synergist oxidation of hydroquinones (H2Q), thus, we synthesized and characterized dibenzotetraaza [14]annulene type macrocycles of FeIII and CoII metal ions and described by utilizing different examinations inc...

Quasi-equal clock reduction for networks of timed automata replaces clocks in equivalence classes by representative clocks. An existing approach which reduces quasi-equal clocks and does not constrain the support of properties of networks, yields significant reductions of the overall verification time of properties. However, this approach requires strong assumptions on networks in order to soun...

High valence states in manganese clusters are a key feature of the function of one of the most important catalysts found in nature, the water-oxidizing complex of photosystem II. We describe a detailed electrochemical investigation of two bio-inspired manganese-oxo complexes, [Mn(4)O(4)L(6)] (L = diphenylphosphinate (1) and bis(p-methoxyphenyl)phosphinate (2)), in solution, attached to an elect...