Cross-linking the micelles of 4-dodecyloxybenzyltripropargylammonium bromide by 1,4-diazidobutane-2,3-diol in the presence of azide-functionalized imidazole derivatives yielded surface-cross-linked micelles (SCMs) with imidazole groups on the surface. The resulting water-soluble nanoparticles were found, by fluorescence spectroscopy, to contain hydrophobic binding sites. The imidazole groups pr...

We have achieved an Ir(III)-catalyzed temperature-controlled divergent synthesis of tetrasubstituted alkenes and pyrrolo[1,2-a]indole derivatives through C?H alkenylation/DG migration [3+2] annulation, respectively. This method has various advantageous features: a) excellent regio- stereoselectivity good functional group tolerance, b) broad substrate scope moderate to yields, c) mild redox-neut...

Chem. Abstr. Serv. Reg. No.: 60-56-0 Deleted CAS Reg. Nos: 4708-61-6; 85916-84-3 Chem. Abstr. Name: 1,3-Dihydro-1-methyl-2H-imidazole-2-thione IUPAC Systematic Names: 1-Methylimidazole-2-thiol; 1-methyl-4-imidazoline-2thione Synonyms: 2-Mercapto-1-methyl-1H-imidazole; 2-mercapto-1-methylimidazole; mercazolylum; 1-methyl-1,3-dihydroimidazole-2-thione; N-methylimidazolethiol; 1-methyl-2-imidazole...

the stability constants of species present in the systems ni(ii)-pyridoxamine(pym)(a) and ni(ii)-pyridoxamine(pym)(a)-imidazole containing ligands(b) [b = imidazole(him),  benzimidazole(bim), histamine(hist) and l-histidine(his)] have been determined ph-metrically using the miniquad computer program. the existence of the species niah, nia and nia2 was proven for the ni(ii)-pym(a) system, wherea...

Imidazole-zinc reverse stain utilizing imidazole and zinc ions for protein visualization on electrophoresis gels was originally introduced in the 1990s (1–3). This method is based on the selective precipitation of imidazolate-zinc complex in the gel (3), except zones where proteins or other macromolecules, such as DNA (4–7) or lipopolysaccharide, are present (4,5,8,9). There are several advanta...

Thermodynamic data for the proton and metal ion complexation equilibria of imidazole ( 1,3 diazole, glyoxaline ) and histamine ( 4-imidoazolethylamine, 4 ( 2’ aminoethyl ) imidazole ) have been collected and critically evaluated. The literature search has been performed by using IUPAC’s “Stability Constants Database” and covers the literature until 1992. Important criteria for acceptance compri...

Imidazole is reported to be an effective reactant for the production of nanocellulose from hardwood pulp. The morphologies and surface properties of the nanocellulose can be simply tailored according to the water content in the imidazole system: with pure imidazole, cellulose nanofibrils (CNFs) in a yield of 10 wt % can be produced. With 25 wt % of water in imidazole, cellulose nanocrystals (CN...

By reaction of a 1-unsubstituted imidazole (imH) with alkali and R 3'PAuC1 under phase trans­ fer conditions or in M eO H solution R3'PAu (im-./V) compounds were obtained where R' = C6H n or r-Bu, and imH was imidazole, 2-/-Pr-, 4 -N 0 2-imidazole or benzimidazole. When the Ph,Sb (or Ph3As) hom ologue was reacted, polymeric [u-(2-methylimidazolato-Ar,/V')gold(I)]„ was obtained, together with (P...