Due to its special electronic and ballistic transport properties, graphene has attracted much interest from researchers. In this study, platinum (Pt) nanoparticles were deposited on oxidized graphene sheets (cG). The graphene sheets were applied to overcome the corrosion problems of carbon black at operating conditions of proton exchange membrane fuel cells. To enhance the interfacial interacti...

Nitrogen doped diamond-like carbon thin films with or without platinum and ruthenium incorporation (N-DLC or PtRuN-DLC) were deposited on highly conductive p-Si substrates by DC magnetron sputtering to study the effect of Pt and Ru doping on the voltammetric performance of the N-DLC films. The potential windows of these film electrodes were measured in different electrolytic solutions, such as ...

We report Pt-Pd nanoparticles synthesized by means of a polyol process with glycerol as a reducing agent. The Pt-Pd nanoparticles exhibit dominantly exposed {111} facets in octahedral shape with complete alloy formation between Pt and Pd. Furthermore, the octahedral Pt-Pd alloy catalysts show improved catalytic activity and stability in methanol electrooxidation.

the silica supported platinum nanoparticles was synthesized by using the sol-gel method. the possibility of using diamminedinitro platinum (ii) as pt precursor and effect of metal precursor concentration on the final pt nanoparticle size was investigated. a stable silica sol was prepared via hydrolysis of tetraethyl orthosilicate (teos) as a metal alcoxide and condensation reaction. subsequentl...

With an eye toward using surface morphology to enhance heterogeneous catalysis, Pt nanoparticles are grown by atomic layer deposition (ALD) on the surfaces of SrTiO(3) nanocubes. The size, dispersion, and chemical state of the Pt nanoparticles are controlled by the number of ALD growth cycles. The SrTiO(3) nanocubes average 60 nm on a side with {001} faces. The Pt loading increases linearly wit...

This paper discusses the mechanisms of surface area loss of supported platinum (Pt) electrocatalysts in lowtemperature fuel cells. It is argued that submonolayer dissolution of Pt nanoparticles governs the surface area loss at high voltages by increasing the loss of Pt from carbon and coarsening of Pt nanoparticles on carbon.

Monolayer-protected transition metal nanoparticles are a unique family of functional nanomaterials in which the properties of the materials can be readily manipulated not only by the chemical nature of the metal cores and the organic protecting ligands, but also the metal–ligand interfacial bonding interactions. The latter is largely motivated by recent progress in nanoparticle passivation by m...

Surface Organo-Metallic Chemistry on Metals (SOMC/M) [1] provides access to a new type of materials. The strategy is to create catalytically active sites which are homogeneously dispersed and uniform in their structure by grafting organometallic precursors on well defined metallic surfaces. For example, tetrabutyltin reacts with the surface of metallic particles supported on silica leading to f...

The use of density functional theory (DFT) and time-dependent DFT (TD-DFT) to study the photochemistry of metal complexes is becoming increasingly important among chemists. Computational methods provide unique information on the electronic nature of excited states and their atomic structure, integrating spectroscopy observations on transient species and excited-state dynamics. In this contribut...