Pristine and Defective Graphene Supports As platinum-based materials are among the most efficient catalysts for electrochemical processes in proton exchange membrane fuel cells, especially oxygen reduction reaction, several groups have shown that support material has a major influence on coordinative stabilization modification of reactivity Pt-cluster-graphene combined material. In article numb...

Proton exchange membranes for fuel cells were synthesized from the blend of copolymers of vinyl acetate-acrylic ester and styrene-acrylic ester, which were modified by sulfonation and addition of silica gel. Water uptake, ion exchange capacity, infrared spectroscopy and tensile tests were applied to characterize the prepared membranes. The results show that the prepared membranes with the proce...

output characteristics of fuel cells are affected by a large number of parameters such as geometry, dimensions, construction materials and conditions of supplying fluids. in this paper a mathematical model followed by a two-dimensional numerical approach has been presented to study the fuel cell parametrically. effect of oxygen concentration at gas diffusion layer entrance, temperature and pres...

We show that the asymmetry in the fractional energy of charm versus an-ticharm jets produced in high energy diffractive photoproduction is sensitive to the interference of the Odderon (C = −) and Pomeron (C = +) exchange amplitudes in QCD. We predict the dynamical shape of the asymmetry in a simple model and estimate its magnitude to be of the order 15% using an Odd-eron coupling to the proton ...

Proton-energy differences, ammonia adsorption, and D/H-exchange barriers for methane at selected isolated Brønsted sites in zeolites FAU, MFI, BEA, ERI, and CHA are studied by combined quantum-chemicalclassical (QM/MM) calculations in an attempt to understand the factors that determine the reactivity at these Brønsted sites. The barrier of the D/H-exchange reaction for methane was found to corr...

Radiation-produced electrons initiate various reaction processes that are important to radiation damage to biomolecules. In this work, the site of attachment of the prehydrated electrons with methylacetoacetate (MAA, CH3-CO-CH2-CO-OCH3) at 77 K and subsequent reactions of the anion radical (CH3-CO•-CH2-CO-OCH3) in the temperature range (77 to ca. 170 K) have been investigated in homogeneous H2O...

The catalytic activity of carbon supported Pd-Co-Mo for the oxygen reduction reaction (ORR) in a single cell proton exchange membrane fuel cell (PEMFC) has been investigated at 60 degrees C and compared with data from commercial Pt catalyst and our previously reported Pd-Co-Au and Pd-Ti catalysts. The Pd-Co-Mo catalyst with a Pd:Co:Mo atomic ratio of 70:20:10 exhibits slightly higher catalytic ...

Neutron dose is transferred to biological materials through the recoil protons produced by elastic scattering. When a low-velocity proton collides with the atoms or molecules of a target, it changes to a hydrogen atom by electron capture; this hydrogen atom then changes to a proton by losing the electron. Because the hydrogen atom has a different ionization cross section from that of a proton, ...

2',7'-Difluorofluorescein (Oregon Green 488) is a new fluorescein-based dye, which has found many applications, above all in biochemistry and neurosciences, and its use has become very popular in the last years. In recent years, we have been investigating the excited-state proton exchange reactions of fluorescein and the effect of suitable proton acceptors and donors which promote these reactio...