Weproposeanewdefinitionof excessadsorption foruse inmolecularmodels of adsorption. Thisdefinition implies the calibration of theoreticalmodels inamannermimicking the experimental calibrationprocedure. The method of theoretical calibration is developed on the example of helium calibration. The notions of the He calibrated pore volume and the He calibrated pore size are introduced, and the He cal...

We investigate the dynamics of a droplet on a planar substrate as the droplet volume changes dynamically due to liquid being pumped in or out through a pore. We adopt a diffuse-interface formulation which is appropriately modified to account for a localized inflow-outflow boundary condition (the pore) at the bottom of the droplet, hence allowing to dynamically control its volume, as the droplet...

The objective of this work was to develop a fast and significant method for the determination of the intraparticulate pore size distribution of microspheres. Poly(lactide-co-glycolide) (PLGA) microspheres prepared with a solvent extraction/evaporation process were studied. From the envelope and the skeletal volume of the microspheres the porosity was calculated. The skeletal volume was determin...

Continuous filtration of fine particles involves filter cake formation and removal of surface moisture by drawing air through the pore structure network. Conventional network theory can be use to study the phenomena of flow through a porous structure by treating the pores as discrete volumes and connecting these with pore throats as resistances of zero volume. In this regard, analysis of the po...

Characterization of the pore structure of compacted and sintered parts made from a nickel-base powder was accomplished using the mercury porosimetry method. The theoretical density values for the sintered specimens varied from 56.3 to 96.7% which corresponds to a porosity of 43.7 to 3.3%. A maximum interconnecting median pore diameter of 21 mum resulted from a -80/+200 mesh powder compacted at ...

A simple porous gel synthesis method is proposed in this paper. We found that the sequential modification of conventional radical polymerization gives rise to pore formation in acrylamide gels and investigated the parameters that are responsible for controlling the number and the size of pores. Pore formation is dominated by the amount of polymerization initiator (ammonium persulfate), accelera...

Macroporous ceramics exhibit an intrinsic strength variability caused by the random distribution of defects in their structure. However, the precise role of microstructural features, other than pore volume, on reliability is still unknown. Here, we analyze the applicability of the Weibull analysis to unidirectional macroporous yttria-stabilized-zirconia (YSZ) prepared by ice-templating. First, ...

We investigate the dynamics of a droplet on a planar substrate as the droplet volume changes dynamically due to liquid being pumped in or out through a pore. We adopt a diffuse-interface formulation which is appropriately modified to account for a localized inflow-outflow boundary condition (the pore) at the bottom of the droplet, hence allowing to dynamically control its volume, as the droplet...

This research is a part of a wide range investigation on the use of flue gas desulphurisation (FGD) in construction applications. It reports some results on the porosity and pore size distribution of cement paste containing varying amounts of fly ash-gypsum blends as partial replacement of cement. The cement was replaced with 25% of different blends of fly ash and gypsum. The gypsum content ran...

Although there is no assumption of pore geometry in derivation of Gassmann’s equation, the pore geometry is in close relation with hygroscopic water content and pore fluid communication between the micropores and the macropores. The hygroscopic water content in common reservoir rocks is small, and its effect on elastic properties is ignored in the Gassmann theory. However, the volume of hygrosc...