A continuing goal in catalysis is to unite the advantages of homogeneous and heterogeneous catalytic processes. To this end, nanoparticles represent a new frontier in heterogeneous catalysis, where this unification can also be supplemented by the ability to obtain new or divergent reactivity and selectivity. We report a novel method for applying heterogeneous catalysts to known homogeneous cata...

Catalytic hydrosilylation represents a straightforward and atom-efficient methodology for the creation of C-Si bonds. In general, the application of homogeneous platinum complexes prevails in industry and academia. Herein, we describe the first heterogeneous single atom catalysts (SACs), which are conveniently prepared by decorating alumina nanorods with platinum atoms. The resulting stable mat...

The optical frequency doubling properties of silver, copper, and platinum nanoparticles in aqueous solution are studied via hyper-Rayleigh scattering (HRS) spectroscopy. Substantial HRS responses are observed for silver and copper particles. The response is attributed to enhancement due to resonance of the nonlinearly scattered light with the particles’ surface plasmon absorption band. Platinum...

A first-principles model of the electrochemical double layer is applied to study surface energies and surface coverage under realistic electrochemical conditions and to determine the equilibrium shape of metal nanoparticles as a function of applied potential. The potential bias is directly controlled by adding electronic charge to the system, while total energy calculations and thermodynamic re...

Energy migrations at metal nanomaterial surfaces are fundamentally important to heterogeneous reactions. Here we report two distinctive energy migration pathways of monolayer adsorbate molecules on differently sized metal nanoparticle surfaces investigated with ultrafast vibrational spectroscopy. On a 5 nm platinum particle, within a few picoseconds the vibrational energy of a carbon monoxide a...

gas diffusion electrode was used for providing better conditions in fuel cell systems for oxygen reduction reaction (orr). because the slow kinetics of the oxygen reduction reaction at the proton exchange membrane fuel cell cathode restricts fuel cell efficiency. to this end, researchers have used platinum-coated carbon. in the present study, due to the reduction of carbon corrosion, zinc oxide...

Introduction Gliomas are the most aggressive and common primary tumors of the central nervous system (CNS). Many side effects of drugs containing platinum and their poor penetration of the CNS are major drawbacks in glioma therapy. The aim of the study was to investigate and compare the toxicity of platinum nanoparticles and cisplatin and their anticancer properties in examination with a U87 gl...

BACKGROUND Platinum nanomaterial is one of the significant noble metal catalysts, and the interaction of platinum with microbe is one of the key factors in influencing the size and the distribution of the platinum nanoparticles on the microbial biomass. Some properties of Pt(IV) adsorption and reduction by resting cells of Bacillus megatherium D01 biomass have once been investigated, still the ...

Atomic Layer Deposition of Platinum on Strontium Titanate Surfaces Tremendous energy savings and environmental benefits are possible from improved catalysts for chemical manufacturing and emissions reduction. Breakthroughs in catalyst development will be enabled by precise methods for synthesizing nanostructured materials. Atomic layer deposition (ALD) is a thin film growth technique that is cu...