Copper sulfide nanotubes and nanoparticles have been successfully synthesized by a hydrothermal process at 160 °C for 10 h, employing copper chloride (CuCl2·2H2O) and thioacetamide as starting materials, polyethylene glycol 400 as surfactant. The products are characterized by X-ray power diffraction, scanning electron microscopy, UV–vis spectroscopy and fluorescence spectroscopy, respectively. ...

Hydrogen evolution from photocatalytic reduction of water holds promise as a sustainable source of carbon-free energy. Covalent organic frameworks (COFs) present an interesting new class of photoactive materials, which combine three key features relevant to the photocatalytic process, namely crystallinity, porosity and tunability. Here we synthesize a series of water- and photostable 2D azine-l...

Photocatalytic degradation of an organic dye, emerald green, on nano titanium dioxide (anatase 99.5%) at basic buffer pH of 7, 8 and 9 has been investigated. The effects of various operating parameters such as initial concentration of dye, catalyst dosage, bufferic pH and irradiation time on photocatalytic degradation have been studied in a photoreactor cell containing high pressure mercury lam...

Tuning the photonic band gap (PBG) to the electronic band gap (EBG) of Au/TiO2 catalysts resulted in considerable enhancement of the photocatalytic water splitting to hydrogen under direct sunlight. Au/TiO2 (PBG-357 nm) photocatalyst exhibited superior photocatalytic performance under both UV and sunlight compared to the Au/TiO2 (PBG-585 nm) photocatalyst and both are higher than Au/TiO2 withou...

The influence of halide ions on the photocatalytic process on titanium dioxide has been investigated carefully. Chloride and bromide ions, acting as hole scavengers, generate active radical species (e.g., ·Cl and ·Br) that participate in reactions with the organic compounds and the transient intermediates. Chloride and bromide ions have shown to deeply inhibit the degradation rate of chloroform...

Background & Aims of the Study: Pharmaceutical compounds have a variety of forms and applications. Specific amounts of toxic organic compounds in the process of their manufacturing and utilization cause environmental pollution problems. So, degradation and removal these compounds are necessary. The aim of this paper is the study photocatalytic degradation of ciprofloxacin drug in aqueous soluti...

It has been shown that the photocatalytic activity of doped semiconductor with some nonmetals is higher than a pure semiconductor. Hence, with an attempt to achieve higher photocatalytic activity, doped ZnO with C, N, and S was prepared by a sedimentary process and used for the photocatalytic degradation of Fluocinolone Acetonidin as a drug in aqueous solutions.  ...

Er-doped BiVO4 are synthesized by means of a surfactant free microwave assisted hydrothermal method having good photoactivities under sun-like excitation for the degradation of methylene blue. From the structural and morphological characterization, it has been stated that the presence of Er(3+) induces a slight stabilization of the tetragonal phase, probably due to its incorporation in the BiVO...

Novel carbon quantum dot (CQD)-modified BiOI photocatalysts were prepared via a facile hydrothermal process. The CQD-modified BiOI materials were characterized by multiple techniques. The CQD with an average size around several nanometers was distributed on the surface of BiOI microsphere. Its photocatalytic activity was investigated sufficiently by the photodegradation of methylene orange (MO)...