In the present work advanced oxidation process, photo-Fenton (UV/H2O2/Fe) system, for the treatment of wastewater contaminated with oil was investigated. The reaction was influenced by the input concentration of hydrogen peroxide H2O2, the initial amount of the iron catalyst Fe, pH, temperature and the concentration of oil in the wastewater. The removal efficiency for the system UV/ H2O2/Fe at ...

Due to their excellent properties, clays have been widely used in several applications, particularly in catalysis. In this paper, three clays were used as heterogeneous photo-Fenton catalysts for phenol and tyrosol oxidations. Particular attention was given to the effect of the main operating conditions on the process performance. A total conversion was obtained for both organic pollutants with...

The Suzuki coupling reaction is one of the most practiced classes of catalytic C-C bond formation. The development of newmeans of activating molecules and bonds over old catalysts for C-C bond formation is a fundamental objective for chemists. Here, we report the room-temperature C-C bond formation over heterogeneous Pd catalysts by light-mediated catalyst activation. We employ stimulated elect...

polydimethylsiloxane (pdms) has been synthesized by ring-opening polymerization of octamethylcyclotetrasiloxane (d4) in microemulsion with acidic catalyst. the structure and properties of microemulsion were characterized by transmission electron microscopy (tem), fourier transform infrared spectroscopy (ft-ir), photo correlation spectroscopy (pcs). the effect of the variation in ph value, amoun...

Summarization of electronic discussion fora is a unique challenge; techniques that work startlingly well on monolithic documents tend to fare poorly in this informal setting. Additionally, conventional techniques ignore much of the structures that have the potential to serve as valuable features in the summarization task. We present several novel examples of such features, including the catalys...

this study deals with employing foundry sand (fs) as new low cost iron source in heterogeneousphoto-fenton process for the degradation of herbicide isoproturon (ipu) in aqueous solution. thecharacterization of the fs by eds confirmed presence of iron (23%) required for photo-fenton andsimultaneously confirmed absence of any heavy metals which may be susceptible to leaching. the photo-fenton eff...

Photocatalytic systems for the reduction of aqueous protons are strongly pH-dependent, but the origin of this dependency is still not fully understood. We have studied the effect of different degrees of acidity on the electron transfer dynamics and catalysis taking place in a homogeneous photocatalytic system composed of a phosphonated ruthenium tris(bipyridine) dye (RuP) and a nickel bis(dipho...

Photocatalytic systems for the reduction of aqueous protons are strongly pH-dependent, but the origin of this dependency is still not fully understood. We have studied the effect of different degrees of acidity on the electron transfer dynamics and catalysis taking place in a homogeneous photocatalytic system composed of a phosphonated ruthenium tris(bipyridine) dye (RuP) and a nickel bis(dipho...

In this research we first synthesized MgFe2O4 nanostructures via hydrothermal method using (Mg(NO₃)₂.6H₂O) and (Fe(NO₃)₃.9H₂O). The influence of concentration, surfactant, precipitating agent and temperature on the particle size and magnetic properties of the synthesised nanoparticles were examined. Then MgFe2O4-Ag nanocomposites were prepared by a simple chemical precipitation. The structural ...