Novel in-situ reduction approach was applied for the synthesis of palladium nanoparticles in the pores of mesoporous silica materials with grafted silicon hydride groups. Matrices possessing different structural properties (MCM-41, SBA-15 and Silochrom) were used. Samples were studied by nitrogen adsorption-desorption method, low-angle X-ray diffraction, transmission electron microscopy (TEM) a...

Palladium nanoparticles can be prepared by reduction of palladium(II) chloride in the presence of different compounds featuring long perfluorinated carbon chains.

Quartz slides bearing layers of a palladium azopyridine complex are seen to liberate catalytic amounts of a soluble active palladium species which can be used for Suzuki coupling.

Today, development of resistance to anticancer drugs (including cisplatin) is noticed as a major problem. Recently several studies demonstrated that palladium complexes showed remarkable cytotoxic effects against K562 cell line and could be used efficiently for treatment of many human cancers including leukemia. Hereof, K562 cells were made resistant to cisplatin using increasing concentration ...

Palladium islands with a thickness of a few monolayers were deposited on top of a self-assembled monolayer (SAM) fabricated from 4-mercaptopyridine. In the I(V) curves obtained using the scanning tunneling microscope (STM) clearly the signature of Coulomb blockade is observed, explicitly demonstrating that these islands are coupled to the underlying gold substrate only via a tunneling barrier; ...

In the context of palladium-catalyzed guanylation of anilines herein, we have been able to characterize and isolate bis(anilino) and bis(guanidino)Pd(II) complexes using reaction conditions under which stoichiometric amounts of palladium salts are used. Characterization of these palladium complexes strongly supports a mechanistic proposal for the catalytic guanylation of anilines using PdCl2(NC...

A new method of preparing 2,2'-bipyridines with short reaction times by using microwave assistance and heterogeneous catalysts has been developed. With a Negishi-like protocol, it was found that Ni/Al(2)O(3)-SiO(2) afforded 2,2'-bipyridine products in up to 86% yield in 1 h. Palladium supported on alumina also provided yields of 2,2'-bipyridines comparable to those seen for homogeneous PEPPSI (...

Major advances in laser technology at LLE have included the demonstration of high-efficiency frequency doubling and tripling of fusion lasers1 and the development of short-pulse, chirped-pulse-amplification (CPA) lasers2 These technologies were combined a few years ago with the demonstration of 75% efficient frequency doubling of 1.6-ps laser pulses on the CPA T~ (table-top terawatt) system at ...

Stopfel, H. 2017. Tailoring the magnetic order in mesoscopic spin systems. Digital Comprehensive Summaries of Uppsala Dissertations from the Faculty of Science and Technology 1574. 78 pp. Uppsala: Acta Universitatis Upsaliensis. ISBN 978-91-513-0099-3. Mesoscopic spin systems can be designed and fabricated using modern nano-fabrication techniques. These systems can contain large numbers of patt...

Fusion of a palladium-binding peptide to an archaeal rhodopsin promotes intimate integration of the lipid-embedded membrane protein with a palladium hydride protonic contact. Devices fabricated with the palladium-binding deltarhodopsin enable light-activated conversion of protonic currents to electronic currents with on/off responses complete in seconds and a nearly tenfold increase in electric...