Diffusion behavior of water, diatomic oxygen, and a mixture of both into a poly(3hexylthiophene)[P3HT] melt were investigated using Molecular Dynamics Simulation. Once simulations were complete, the data was analyzed to determine the diffusion coefficient of those molecules in P3HT using Fick’s law. The diffusion coefficient values were then plotted as a function of concentration and temperatur...

A solution state polymer diode, which uses regioregular poly(3-hexylthiophene-2,5-diyl) (P3HT):dichlorobenzene solution as the semiconductor between highly doped p-type silicon and aluminum electrodes has been built. Electrodes separated by a 40 nm gap enable intra-chain charge carrier transfer through the lengths of single polymer chains. This prevents chain to chain hopping and chain entangle...

The optoelectronic properties of conjugated polymers combined with “plastic” mechanical behavior and solution processability make them highly interesting materials with applications in organic electronics. 5 In bulk heterojunction (BHJ) solar cells, an electron-donating conjugated polymer is blended with a fullerene electron acceptor, such as [6,6]-phenyl C60 butyric acid methyl ester (PCBM). 1...

The optical properties of organic semiconductor thin films deposited on nanostructured surfaces are investigated using time-resolved two-photon photoluminescence (PL) microscopy. The surfaces consist of parallel aligned metallic or dielectric nanowires forming well-defined arrays on glass substrates. Keeping the nanowire dimensions constant and varying only their spacing from 40 to 400 nm, we s...

This is an in depth study on the surface potential changes of P3HT/TiO(2) nanorod bulk heterojunction thin films. They are affected by interlayer structures, the molecular weight of P3HT, the processing solvents and the surface ligands on the TiO(2). The addition of an electron blocking layer and/or the hole blocking layer to the P3HT/TiO(2) thin film can facilitate charge carrier transport and...

All-conjugated block copolymers are an emerging class of polymeric materials promising for organic electronic applications, but further progress requires a better understanding of their microstructure including crystallinity and self-assembly through micro-phase segregation. Here, we demonstrate remarkable changes in the thin film structure of a model series of all-conjugated block copolymers w...

A strategy for the fabrication of high surface area poly(3-hexylthiophene) thin films by removal of nanoscale domains formed from graft copolymers is presented. This approach relies on the synthesis and characterization of cleavable graft copolymers based on regioregular poly(3-hexylthiophene) (rr-P3HT) main chain and sacrificial poly(styrene) side chains. An alkoxyamine initiator based on 2,2,...

Ultrathin ferroelectric polyvinylidene fluoride (70%)-tetrafluoroethylene (30%) copolymer film is inserted between the poly3(hexylthiophene) (P3HT) donor and [6,6]-phenyl-C61-butyric acid methylester (PCBM) acceptor layers as the dipole layer to tune the relative energy levels, which can potentially maximize the open circuit voltage of bilayer organic solar cells. In this work, the power conver...

Airbrushed single walled carbon nanotube (SWCNT) thin films with sheet resistivity <1 kX/ sq. and transparency >80% are used as electrodes for pentacene and regioregular poly(3hexylthiophene) (P3HT) thin-film transistors (TFTs). Airbrushed SWCNT electrodes show low contact resistance in a bottom-contact configuration, comparable to (in the case of P3HT) or lower than (in the case of pentacene) ...

We demonstrate an integration of polymer light-emitting diode ~LED! and polymer transistor in which no patterning of the organic layers is needed. Intrinsic high-mobility semiconducting conjugated polymer poly~3-hexylthiophene!~P3HT! is used as the hole-transport layer for polymer LED. The light emission efficiency is only slightly lower than the LED with conventional heavily doped hole-transpo...