A feasibility study of a conventional fixed-bed reactor and packed-bed membrane (PBMR) in distributor configuration is carried out for the selective oxidation methanol to oxygenates dimethoxymethane methyl formate on VOx/TiO2 catalyst. Kinetic experiments provided reaction network reliable kinetic model six main reactions involved. The PBMR offers significant advantages potential formation both...

Short-chain fatty acids (SCFAs) have been used as raw materials in wide range of chemical and medical applications. One technique to produce SCFAs is oxidative cleavage long-chain (LCFAs). However, unless the LCFAs are unsaturated, yield often very low because carboxylic group acid more active than other part molecule. This work explores idea introducing a double bond into saturated LCFA, i.e.,...

The oxidative dehydrogenation of propane to propene using carbon dioxide is an attractive novel synthesis route produce a key platform chemical. We investigated iron-chromia catalysts prepared by sol-gel. mixed oxides showed improved specific surface area and high concentration acid base sites were found be highly active catalysts. Although coking was observed over the catalysts, regeneration r...

Abstract The oxidative dehydrogenation (ODH) of 1-butene to 1,3-butadiene was studied over a series AFe 2 O 4 catalysts, where A = Zn, Mn, Ni, Cu, Mg and Fe. catalysts were characterised by XPS, EPR spectroscopy, BET surface area analysis, Raman spectroscopy XRD. All the ferrites active for ODH gave an order activity after 80 h on-stream ZnFe > NiFe MnFe MgFe CuFe FeFe . lost significant (up...

A 2,4-diarylquinoline derivative, 2-(4-chlorophenyl)-4-(3,4-dimethoxyphenyl)-6-methoxy-3-methylquinoline, was synthesized in a conventional two-step procedure from p-anisidine, p-chlorobenzaldehyde and methyl isoeugenol as available starting reagents through sequence of BF3·OEt2-catalyzed Povarov cycloaddition reaction/oxidative dehydrogenation aromatization processes under microwave irradiatio...