Methane is the fundamental raw material of C1 chemical industry, with abundant reserves. Its direct conversion into high-value-added chemicals has great scientific significance and broad commercial potential for efficient use methane resources. However, it difficult to convert more useful hydrocarbons hydrogen, as reaction usually requires external energy overcome thermodynamic limitations. Non...

In the microwave and radio frequency (RF) plasma catalytic reaction at room temperature, the oxidative coupling of methane (OCM) over transitional metals loaded on ZSM-5 has been carried out. The transitional metals, Fe, Ni, Co and Cu (1B family element), loaded on ZSM-5 have been tested for the OCM using the plasma catalytic reaction. In this work, the conversion of methane to C2 products has ...

The rates of C H bond activation for various alkanes by [(N-N)Pt(Me)(TFEd(3))](+) (N N = Ar N C(Me) C(Me) N Ar; Ar = 3,5-di-tert-butylphenyl; TFE-d(3) = CF(3)CD(2)OD) were studied. Both linear and cyclic alkanes give the corresponding alkene-hydride cation [(N-N)Pt(H)(alkene)](+) via (i) rate determining alkane coordination to form a C H sigma complex, (ii) oxidative cleavage of the coordinated...