We follow the evolution of polyoxomolybdate nanoparticles in suspensions derived from the keplerate (NH4)42[MoVI72MoV60O372(CH3CO2)30(H2O)72].ca..300H2O.ca..10CH3CO2NH4 ({Mo132}) by flow field-flow fractionation (FlFFF) to monitor the particle-size distribution in situ, atomic force and high-resolution transmission electron microscopy (AFM, SEM, and HRTEM) to confirm particle sizes, inductively...

The effect of silicon concentration and annealing temperature on terbium luminescence was investigated for thin silicon rich silicon oxide films. The structures were deposited by means of plasma enhanced chemical vapor deposition. The structural properties of these films were investigated by Rutherford backscattering spectrometry, transmission electron microscopy and Raman scattering. The optic...

In this study, grains of two buckwheat species: Fagopyrum esculentum (IC37309) and Fagopyrum tataricum (var. himpriya) were phytochemically investigated for their nutritional, and antioxidant potential for their use as functional foods. Methanolic extracts of grains of two Fagopyrum species showed higher phenolic content and antioxidant activity. Inductively coupled plasma optical emission spec...

A remote detection system based on optical emission spectrometry of laser-induced plasmas has been developed to record spectra in the visible region from samples placed at remote distances from the excitation source. Unlike from fiber-optic-based systems, light collection is performed remotely as well. Laboratory-scale experiments have shown the possibility of performing real-time analysis of s...

We report a simple synthesis of silver:glutathione (Ag:SG) clusters using a cyclic reduction under oxidative conditions. Two syntheses are described which lead to solutions containing well-defined Ag31(SG)19 and Ag15(SG)11 clusters that have been characterized by mass spectrometry. The optical properties of silver:glutathione (Ag:SG) cluster solutions have been investigated experimentally. In p...

Silicon nanocrystals embedded in silicon nitride films were irradiated with Si-ions at 8 MeV in order to modify their optical response. The samples were characterized by means of Rutherford Backscattering Spectrometry, Elastic Recoil Detection Analysis, High-Resolution Transmission Electronic Microscopy and Photoluminescence analysis. It was found a blue-shift in the photoluminescence emission ...

Optical Emission Spectroscopy and Rutherford Backscattering Spectrometry are combined to determine condensation coefficients for plasma sputtering deposition. The method is applied for palladium deposition onto various substrates and condensation coefficients are found to lie between 0.4 and 0.9. PACS numbers: 81.15.Cd, 52.77.Dq Submitted to: J. Phys. D: Appl. Phys. § Corresponding author: Fax ...

A simple design for a cesium sputter ion source compatible with vacuum and ion-optical systems as well as with electronics of the commercially available Cameca IMS-4f instrument is reported. This ion source has been tested with the cluster primary ions of Si(n)(-) and Cu(n)(-). Our experiments with surface characterization and depth profiling conducted to date demonstrate improvements of the an...

concentrations of major nutritional and trace elements (ca, p, mg, na, k, fe, zn, cu, mn, se,co, cr, ni, sr, ba) and toxic heavy metals (cd, pb) were analyzed in the meat of limousin, red angus andsalers bulls. elements were determined using inductively coupled plasma emission atomic spectrometry. theconducted research showed that the meat of compared breeds differed in the concentrations of cu...