We propose another way of getting to the bottom of nucleation by using finite volume systems. Here we show, using a sharp tip, that a single nucleation event is launched as soon as the tip touches the supersaturated confined metastable solution. We thus control spatial and temporal location and demonstrate that confinement allows us to carry out predictive nucleation experiments. This control i...

We consider the dynamics of diffusing particles in one space dimension with annihilation on collision and nucleation (creation of particles) with constant probability per unit time and length. The cases of nucleation of single particles and nucleation in pairs are considered. A new method of analysis permits exact calculation of the steady state density and its time evolution in terms of the th...

A method is presented for calculating ion-induced nucleation rates. Whereas classical ion-induced nucleation theory makes the approximation that small ionic clusters are charged droplets whose properties equal their values for the bulk liquid, the method presented gives a nucleation rate in the form of a summation over discrete cluster properties. The summation converges rapidly around the crit...

This paper analyzes the effect of mixing on nucleation of protein crystals. The mixing of protein and precipitant was controlled by changing the flow rate in a plug-based microfluidic system. The nucleation rate inversely depended on the flow rate, and flow rate could be used to control nucleation. For example, at higher supersaturations, precipitation happened at low flow rates while large cry...

[1] Recently, we have shown that the binary homogeneous nucleation (BHN) of H2SO4 and H2O can be treated as a quasi-unary nucleation (QUN) of H2SO4 in the equilibrium with H2O vapor and have developed a kinetic H2SO4-H2O nucleation model, which simulates the dynamic evolutions of cluster distributions explicitly. In this paper we present improved and updated version of the QUN model, which has ...

Aerosol nucleation events have been observed at a variety of locations worldwide, and may have significant climatic and health implications. Binary homogeneous nucleation (BHN) of H2SO4 and H2O is the foundation of recently proposed nucleation mechanisms involving additional species such as ammonia, ions, and organic compounds, and it may dominate atmospheric nucleation under certain conditions...

Hollow nanoparticles (NPs) are produced by void nucleation and growth during chemical reactions. However, there is no proper understanding of nucleation and growth mechanisms and their predictive modeling. Models based on the Kirkendall effect predict the process time, which is larger by orders of magnitude than in experiment. This is why some works propose that a large tensile pressure in the ...

Classical nucleation theory is unable to explain the ubiquity of nucleation events observed in the atmosphere. This shows a need for an empirical determination of the nucleation rate. Here we present a novel inverse modeling procedure to determine particle nucleation and growth rates based on consecutive measurements of the aerosol size distribution. The particle growth rate is determined by re...

The formation of crystalline nanoparticles starts with nucleation and control of nucleation is crucial for the control of the number, size, perfection, polymorph modification and other characteristics of particles. Recently, there have been significant advances in the understanding of the mechanism of nucleation of crystals in solution. The most significant of these is the two-step mechanism of...

Nucleation in supersaturated vapor is investigated with two series of molecular-dynamics simulations in the canonical ensemble. The applied methods are (a) analysis of critical nuclei at moderate supersaturations by simulating equilibria of single droplets with surrounding vapors in small systems; (b) simulation of homogeneous nucleation during condensation with large systems containing 10(5)-1...