In this work, the feasibility of nuclear processes is studied via classical thermodynamics by assessing change in entropy, a parameter that has so far been neglected analysis these reactions. The contribution entropy to reaction spontaneity plays different role fission and fusion particular, reactions temperature acts as very powerful amplifier entropic term (−T ΔS) that, at tokamaks (millions ...

a type of novel hypercross-linked fiber adsorbent was obtained by sulfonation and cross-linking reaction of polypropylene fiber grafted styrene-divinylbenzene. the aim of the fiber sulfonation and cross-linking method was to prepare rigid three dimensional networks in the entire fiber and change the ion exchange capacity of fiber. the hypercross-linked fiber adsorbent possesses a principally di...

important thermodynamic parameters including denaturant equilibrium m values (meq) and heat capacity changes (δcp) can be predicted based on changes in solvent accessible surface area (sasa) upon unfolding. crosslinks such as disulfide bonds influence the stability of the proteins by decreasing the entropy gain as well as reduction of sasa of unfolded state. the aim of the study was to develop ...

Lys(63)-linked polyubiquitin (poly-Ub) chains appear to play a nondegradative signaling and/or recruitment role in a variety of key eukaryotic cellular processes, including NF-kappaB signal transduction and DNA repair. A protein heterodimer composed of a catalytically active ubiquitin-conjugating enzyme (Ubc13) and its homologue (Mms2 or Uev1a) forms a catalytic scaffold upon which a noncovalen...

Thermodynamics is unique among physical and chemical descriptions of our surroundings in that it does not rely on a detailed knowledge of any interior structure of the systems to which it pertains but rather treats such systems as “black boxes” whose equilibrium states are determined by the surroundings with which they can coexist and which can be described by a few parameters. This feature ass...

Using the generalized procedure proposed by Wu et al23 recently, we construct the first law of thermodynamics on apparent horizon in a general braneworld model with curvature correction terms on the brane and in the bulk, respectively. The explicit entropy formulary of apparent horizon in the general braneworld is worked out. We also discuss the masslike function which associated with a new typ...

Preservation of genetic information in DNA relies on shielding the nucleobases from damage within the double helix. Thermal fluctuations lead to infrequent events of the Watson-Crick basepair opening, or DNA "breathing", thus making normally buried groups available for modification and interaction with proteins. Fluctuational basepair opening implies the disruption of hydrogen bonds between the...

Proton nuclear magnetic resonance (1H NMR) experiments have been performed to measure the spin-lattice, T1, and spin-spin, T2, relaxation times of the three functional groups in water/methanol mixtures at different methanol molar fractions (XMeOH=0, 0.04, 0.1, 0.24, 0.5, 1) as a function of temperature in the range 205 K<T<295 K. The measured relaxation times in the mixtures, at all the methano...

A longer-than-unit-length transcript of potato spindle tuber viroid is correctly processed in a potato nuclear extract only if the central conserved region is folded into a multi-helix junction containing at least one GNRA tetraloop-hairpin. The cleavage-ligation site between G95 and G96 was mapped with S1 nuclease and primer extension. The structural motifs involved in the processing mechanism...

The existing thermodynamics of the cosmological horizon in de Sitter spacetime is established in the micro-canonical ensemble, while thermodynamics of black hole horizons are established in the canonical ensemble. Generally in the ordinary thermodynamics and statistical mechanics, both of the micro-canonical and canonical ensembles yield the same equation of state for any thermodynamic system. ...