A novel, highly active catalyst Ni@MOF-5 showed unexpected activity at low temperature for CO2 methanation. The characterization results indicated that Ni was uniformly and highly dispersed over MOF-5. This catalyst showed high stability and almost no deactivation in long term stability tests up to 100 h.

Base metal promoted gold/titania catalysts were synthesized, characterized and tested in CO oxidation reaction. Catalysts containing dopant metals in higher oxidation states exhibited higher activity than catalysts containing dopants in reduced states. The activity of fresh catalysts promoted by Cu, Fe and Ni was similar to the unpromoted one, but treatment in reducing and oxidizing atmospheres...

Introduction: The direct use of CH4 as the feed to the solid oxide fuel cell (SOFC) will allow elimination of a reformer, simplifying the SOFC system and decreasing the system cost [1]. The overall reaction on the anode catalyst in the direct CH4 SOFC is the electrochemical oxidation of CH4: CH4 + 4O CO2 + 2H2O + 8e. Due to the nature of hydrocarbon reactions at high temperature and the reducin...

We carried out the carbon nanotubes (CNTs) growth from an Au catalyst with two different kinds of chemical vapor deposition (CVD) methods. In case of thermal CVD (TCVD), high quality single-walled carbon nanotubes (SWNTs) can be grown. On the other hand, only poorly crystallized CNTs are synthesized with plasma CVD (PCVD). Through the parametric investigations, it is found that the hydrogen gas...

This study focuses on the manufacture of carbon nanotubes using the arc discharge method. Several independent variables were changed, such as the current (80 and 100 A), an atmosphere of open air or argon and the catalyst (no catalyst, Fe or a mixture of Fe/Co,Ni). Only one set of parameters yielded MWNTs, involving Fe as the catalyst and an open air atmosphere. I. INTRODUCTION There has been i...

The catalyst formation in the system Ni(acac),, C&I,, (iBu)sAl was investigated by means of infrared spectroscopy. It was found that the Al(acac)s and (iBu)&l(acac) formed are both by-products of catalyst formation without a catalytic activity. Ni(acac)z loses its acac groups forming the unstable (iBu)sNi compound; without CsH, being present, this compound disproportionates to Ni metal and isob...

Exploiting the greenhouse gas CO2 as raw material could be more advantageous than its long-term storage. For instance, CO2 can be used on large scale for the production of COrich syngas with a H2/CO ratio of unity. Such a syngas can be used for the synthesis of commodity chemicals like aldehydes and ketones obtained through carbonylation of alkenes in hydroformulation and can be produced by CO2...

Synthesis of low cost, durable and efficient electrocatalysts that support oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) are the bottlenecks in water electrolysis. Here we propose a strategy for the development of controllably alloyed, porous, and low density nickel (Ni) and cobalt (Co) based alloys - whose electrocatalytic properties can be tuned to make them multifunct...

Ni/Al2O3 is an active catalysts for CO2 hydrogenation to both CH4 and CO. By doping with Ga, we succeeded in shifting the selectivity of these almost completely toward In-situ IR spectroscopy studies showed that catalyst activity directly related concentration surface hydroxyl groups are responsible adsorption formation intermediate bicarbonates formates on surface. The addition Ga improved Ni ...

A series of high-quality M2(BDC)2(DABCO) metal-organic frameworks (abbreviated as M-DABCO; M=Zn, Co, Ni, Cu; BDC=1,4-benzene dicarboxylate; DABCO=1,4-diazabicyclo[2.2.2]octane), were synthesized by using a solvothermal (SV) method, and their catalytic activity for the cycloaddition of CO2 to epoxides in the absence of a co-catalyst or solvent was demonstrated. Of these metal-organic frameworks ...