Abstract Due to the important role of cocatalyst in polymerization process employing industrially favored Ziegler–Natta catalysts, its effect on kinetic behavior, catalyst activity, and polymer properties is discussed. In this paper, triethyl aluminum (TEA) triisobutyl (TIBA) have been used as main ingredient with 10–20 mol percent diethyl chloride (DEAC) ethyl dichloride (EADC) cocatalysts, be...

The authors have assessed the possibility of electrochemical synthesis a wide range reagents based on titanium trichloride as part work. Despite growing demand for and its derivatives, production technology this reagent has not been improved long period. Traditional technologies feature high environmental industrial hazards, process itself energy consumption complex hardware scheme. As prelimin...

heterogeneous ziegler-natta and homogeneous metallocene catalysts exhibit greatly different active sitenature in olefin polymerization. in our previous study, it was reported that mgcl2-supported titanocenecatalysts can generate both ziegler-natta-type and metallocene-type active sites according to the type of activators.the dual active site nature of the supported titanocene catalysts was furt...

The interaction of the external donor (propyltrimethoxysilane - PTMS) with titanium-magnesium catalysts (TMCs) containing dibutylphthalate (DBP) as internal donor, which were prepared in different ways, was studied by chemical analysis and infrared diffuse reflectance spectroscopy (DRIFTS). The chemical composition of the catalysts after their interaction with heptane solutions of PTMS, PTMS/Al...

IEC 61508: Effect of Test Policy on the Probability of Failure on Demand of Safety Instrumented Systems Sergio Contini, Sabrina Copelli*, Massimo Raboni , Vincenzo Torretta , Carlo Sala Cattaneo , Renato Rota b a Università degli Studi dell’Insubria Dip. di Scienza e Alta Tecnologia, Via G.B. Vico 46 21100 Varese Italy b Politecnico di Milano Dip. di Chimica, Materiali e Ingegneria Chimica “G. ...

Summarization of electronic discussion fora is a unique challenge; techniques that work startlingly well on monolithic documents tend to fare poorly in this informal setting. Additionally, conventional techniques ignore much of the structures that have the potential to serve as valuable features in the summarization task. We present several novel examples of such features, including the catalys...

Strict morphological control over growing polymer particles is an indispensable requirement in many catalytic olefin polymerization processes. In catalysts with mechanically stronger supports, e. g., polymerization-grade silicas, the emergence of extensive cracks via sectioning fragmentation mechanism requires severe stress build-up polymerizing catalyst particle. Here, we report on three facto...