We developed a new semi-analytical source zone depletion model (SZDM) for multicomponent light nonaqueous phase liquids (LNAPLs) and incorporated this into an existing screening model for estimating cleanup times for chemical spills from railroad tank cars that previously considered only single-component LNAPLs. Results from the SZDM compare favorably to those from a three-dimensional numerical...

A study was conducted to determine the effect of nonaqueous-phase liquids (NAPLs) on the bioavailability of benzo[a]pyrene (BaP) in soil. Sentry 19 oil and pristane reduced the availability of BaP for assimilation by the earthworm Eisenia fetida and for mutagenicity in a rifampicin-sensitive strain of Pseudomonas putida. As much as 80% of the compound could be rendered unavailable to the worms ...

ABSTRACT: Delineation of the NAPL source zone in the vicinity of an oil burn pit (OBP) at Letterkenny Army Depot (LEAD) revealed the presence of source material on both sides of a nearby groundwater divide resulting in a bilobate plume. While the northern lobe of the plume migrating from the OBP had been well defined, the southern lobe of the plume had been previously undetected. An investigati...

We study counter-current imbibition, where a strongly wetting phase (water) displaces non-wetting phase spontaneously under the influence of capillary forces such that the non-wetting phase moves in the opposite direction to the water. We use an approximate analytical approach to derive an expression for saturation profile when the viscosity of the non-wetting phase is non-negligible. This make...

Setting up accurate and user-friendly models of physical, chemical and biological processes is particularly useful for design and optimization of vapor extraction/bioventing (SVE/SBV) systems, and prediction of residual concentrations and remediation time. Despite improvment of model structures, the optimum experiments should be designed for model calibration. The feasibility of parameter estim...

Bioventing is a widely recognized technique for the remediation of petroleum hydrocarbon-contaminated soil. In this study, objective was to identify an optimal mathematical model that balances accuracy and ease implementation. A comprehensive review various models developed bioventing conducted wherein advantages disadvantages each were evaluated compared regarding different numerical methods u...