Elevated nitrate concentrations in groundwater and surface water supplies can negatively impact the quality of environment human health. Recent studies have examined use zero-valent iron technology to treat nitrate-contaminated groundwater. Mechanistic aspects reduction by are unresolved. This project investigated kinetics mechanism under anoxic conditions oxic conditions. Stirred-batch reactio...

In the context of groundwater remediation, an increasing interest was found towards nanoscale and microscale zero-valent iron particles (NZVI and MZVI, respectively). However, MZVI and NZVI are not stable when dispersed in water, due to fast aggregation and sedimentation. Consequently, the use of shear thinning solutions of green biopolymers have been recently studied as viscous carrier fluids ...

Dechlorination reactions at sp(2) C-Cl bonds by a pentaphosphino zero-valent iron (ZVI) complex are proposed to follow an oxidative addition, β-Cl-elimination pathway en route to iron-chloride, iron-hydride and iron-acetylide products, the distribution being dependent on the nature of alkyne produced.

volatile organic compounds (vocs) are in categories of mankind and environmentally harmful materials. some of vocs are also carcinogenic and mutagen. because of expanded application of these compounds as various domestic and industrial usages, prevention of environmental contamination of these compounds is a substantial issue.  in this study, the effect of zero-valent iron nanoparticles applica...

The use of nanoscale zero-valent iron (nZVI) for in situ remediation of a wide scale of environmental pollutants is increasing. Bench and field pilot studies have recorded successful cleanup of many pollutants using nZVI and other iron-mediated nanoparticles. However, a major question remains unanswered: what is the long-term environmental fate of the iron nanoparticles used for remediation? We...

leachate treatment from municipal landfills has been always a major anxiety in waste management due to its high level of various contaminations. in this paper the effect of nanosized zero valent iron particles (nzvi) in fenton process for the treatment of high cod strength landfill leachate was scrutinized. the results corroborated this procedure was fast and efficient. in fact, about 87% of in...

recently, a variety of soils contaminated with heavy metals e.g. cr (vi), have been found in industrial sites. such soil contamination is widely distributed in the world and has now become a serious issue for environment. hexavalent chromium, cr (vi), which is known to be carcinogenic and mutagenic to living organisms, has been utilized for leather tanning, electroplating and in other industrie...

The iron nanoparticle technology has received considerable attention for its potential applications in groundwater treatment and site remediation. Recent studies have demonstrated the efficacy of zero-valent iron nanoparticles for the transformation of halogenated organic contaminants and heavy metals. In this work, we present a systematic characterization of the iron nanoparticles prepared wit...

The structures of nanoscale zero-valent iron (nZVI) particles evolving during reactions, and the reactions are influenced by the evolved structures. To understand the removal process in detail, it is important to investigate the relationships between the reactions and structural evolution. Using high resolution-transmission electron microscopy (HR-TEM), typical evolved structures (sheet copreci...