Based on the hypothesis on the presence of double metal cyanides in the primordial oceans, a series of nano-sized metal(II) hexacyanocobaltate(III) (MHCCo) with the general formula: M3[Co(CN)6]2·xH2O (where M = Zn, Fe, Ni and Mn) has been synthesized. Surface interaction of aromatic amines, namely aniline, 4-chloroaniline, 4-methylaniline and 4-methoxyaniline with MHCCo particles has been carri...

Various substituted aniline derivatives were tested for genotoxicity in several short-term tests in order to examine the hypothesis that a substitution at both ortho positions (2,6-disubstitution) could prevent genotoxicity due to steric hindrance of an enzymatic activation to electrophilic intermediates. In the Salmonella/microsome assay, 2,6-dialkylsubstituted anilines and 2,4,6-trimethylanil...

A sensitive and accurate potentiometric reaction-rate method for the assay of peroxidase (EC 1.11.1.7) and peroxidase-coupled reactions is described. The technique is based on the peroxidase-catalyzed rupture of the covalent C-F bond in certain organo-fluoro compounds in the presence of H202 and the measurement of liberated F by a fluoride ion-selective electrode. In a study screening 26 organo...

let $r$ be a ring‎, ‎and let $n‎, ‎d$ be non-negative integers‎. ‎a right $r$-module $m$ is called $(n‎, ‎d)$-projective if $ext^{d+1}_r(m‎, ‎a)=0$ for every $n$-copresented right $r$-module $a$‎. ‎$r$ is called right $n$-cocoherent if every $n$-copresented right $r$-module is $(n+1)$-coprese-nted‎, ‎it is called a right co-$(n,d)$-ring if every right $r$-module is $(n‎, ‎d)$-projective‎. ‎$r$ ...

mndo semi-empirical scf mo calculations are used to study the pyramidal nitrogen atom inversion and configurational equilibria in the title compounds.

In this article we introduce the notion of n-capable groups. It is shown that every group G admits a uniquely determined subgroup (〖Z^n)〗^* (G) which is a characteristic subgroup and lies in the n-centre subgroup of the group G. This is the smallest subgroup of G whose factor group is n-capable. Moreover, some properties of n-central extension will be studied.

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Let $nin mathbb{N}$. An additive map $h:Ato B$ between algebras $A$ and $B$ is called $n$-Jordan homomorphism if $h(a^n)=(h(a))^n$ for all $ain A$. We show that every $n$-Jordan homomorphism between commutative Banach algebras is a $n$-ring homomorphism when $n < 8$. For these cases, every involutive $n$-Jordan homomorphism between commutative C-algebras is norm continuous.

The kinetics of reaction between 4-methylaniline (1), dimethyl acetylenedicarboxylate (2) and formaldehyde (4) has been theoretically investigated to gain further insight into the reaction mechanism. The results of theoretical calculations were achieved using the ab initio method at the HF/6-311g (d, p) level of theory in gas phase. The mechanism of this reaction had 5 steps. Theoretical kineti...