نتایج جستجو برای: mof 199

تعداد نتایج: 13180  

In the present study, a nanoporous metal organic framework (MOF) based on iron metal and amino terephthalate ligand MIL-101-NH2-Fe has been used as a carrier for loading and in vitro release of 5-flurouracil (5-FU) anticancer drug. The 5-FU drug loaded MOF was 13 wt % by using thermogravimetric analysis (TGA). The 5-FU release was monitored under physiological condition at 37°C, pH 7.4 in simul...

Beygzadeh, Mojtaba , Ganjali, Mohammad Reza , Golbabaei, Farideh , Jahangiri, Mehdi , Kakaei, Hojatolla , Shahtaheri, Sayed Jamaleddin ,

Introduction: Hydrogen sulfide is one of the most important impurities in natural gas. Due to the fact that this gas is hazardous, toxic, corrosive and volatile, therefore, the removal of hydrogen sulfide has been studied using several methods. One of the most known procedures is the adsorption process. In the present study, activated carbon and activated carbon-based composite scaffolds (MOF-5...

2014
Bin Li Daomei Chen Jiaqiang Wang Zhiying Yan Liang Jiang Deliang Duan Jiao He Zhongrui Luo Jinping Zhang Fagui Yuan

The construction of efficient enzyme mimetics for the hydrolysis of peptide bonds in proteins is challenging due to the high stability of peptide bonds and the importance of proteases in biology and industry. Metal-organic frameworks (MOFs) consisting of infinite crystalline lattices with metal clusters and organic linkers may provide opportunities for protease mimic which has remained unknown....

2012
Chao Yang Jiang Wu Sarmistha H. Sinha John M. Neveu Yujun George Zheng

The MYST family of histone acetyltransferases (HATs) plays critical roles in diverse cellular processes, such as the epigenetic regulation of gene expression. Lysine autoacetylation of the MYST HATs has received considerable attention recently. Nonetheless, the mechanism and function of the autoacetylation process are not well defined. To better understand the biochemical mechanism of MYST auto...

2003
Marcus Alanen Ivan Porres

We review the central concepts required from a project and configuration management system for MOF-based models. The necessary features for a model repository and MOF framework are given, as well as suggestions of several algorithms and components.

2012
Mudit Dixit Tuhina Adit Maark Sourav Pal

The effect of light metal (M = Li, Be, Mg, and Al) decoration on the stability of metal organic framework MOF-5 and its hydrogen adsorption is investigated by ab initio and periodic density functional theory (DFT) calculations by employing models of the form BDC:M2:nH2 and MOF-5:M2:nH2, where BDC stands for the benzenedicarboxylate organic linker and MOF5 represents the primitive unit cell. The...

Journal: :Journal of the American Chemical Society 2017
Kyung Min Choi Dohyung Kim Bunyarat Rungtaweevoranit Christopher A Trickett Jesika Trese Deniz Barmanbek Ahmad S Alshammari Peidong Yang Omar M Yaghi

Materials development for artificial photosynthesis, in particular, CO2 reduction, has been under extensive efforts, ranging from inorganic semiconductors to molecular complexes. In this report, we demonstrate a metal-organic framework (MOF)-coated nanoparticle photocatalyst with enhanced CO2 reduction activity and stability, which stems from having two different functional units for activity e...

Journal: :Physical chemistry chemical physics : PCCP 2016
Zamirbek Akimbekov Di Wu Carl K Brozek Mircea Dincă Alexandra Navrotsky

The inclusion of solvent in metal-organic framework (MOF) materials is a highly specific form of guest-host interaction. In this work, the energetics of solvent MOF-5 interactions has been investigated by solution calorimetry in 5 M sodium hydroxide (NaOH) at room temperature. Solution calorimetric measurement of enthalpy of formation (ΔH(f)) of Zn4O(C8H4O4)3·C3H7NO (MOF-5·DMF) and Zn4O(C8H4O4)...

2017
Eugene A. Kapustin Seungkyu Lee Ahmad S. Alshammari Omar M. Yaghi

Despite numerous studies on chemical and thermal stability of metal-organic frameworks (MOFs), mechanical stability remains largely undeveloped. To date, no strategy exists to control the mechanical deformation of MOFs under ultrahigh pressure. Here, we show that the mechanically unstable MOF-520 can be retrofitted by precise placement of a rigid 4,4'-biphenyldicarboxylate (BPDC) linker as a "g...

Journal: :Journal of nutritional science and vitaminology 1979
S Kasai S Yamanaka S C Wang K Matsui

Two new 8-O-alkyl derivatives of riboflavin (RF), i.e., 8-methoxy- (MOF), and 8-ethoxy-8-demethyl-D-riboflavin (EOF), their tetraacetate, and the tetraacetate of 8-hydroxy-8-demethyl-D-riboflavin (HOF) were synthesized. The anti-RF activity of MOF, EOF and HOF was estimated from the ratio CR/CI, where CI is the concentration of test flavin added to the culture medium and CR is the minimum conce...

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