The reaction of Mn(ClO4)2·6H2O, a derivatised phenolic oxime (R-saoH2) and the ligand tris(2-pyridylmethyl)amine (tpa) in a basic alcoholic solution leads to the formation of a family of cluster compounds of general formula [Mn(III)2O(R-sao)(tpa)2](ClO4)2 (1, R = H; 2, R = Me; 3, R = Et; 4, R = Ph). The structure is that of a simple, albeit asymmetric, dimer of two Mn(III) ions bridged through ...

the reaction between ni(ii), co(ii), cr(iii) bitrates, ni(ii) chloride and ambidentate a-keto ylide benzoylmethylenetriphenylphosphine (bppy) resulted in isolation of [ni(bppy)2](no3)2.2h2o, [ni(bppy)2]cl2, [co(bppy)2](no3)2 and [cr(bppy)3](no3)3; 2h2o. the compounds were characterized by elemental analyses and infrared 1hnmr spectroscopy, molar conductivity in solution and molecular weight mea...

background: the incorporation of thallium-201 into 8-hydroxyquinoline was targeted for cell labeling due to interesting physical properties and wide availability of this nuclide as a single photon emission computed tomography (spect) radionuclide. materials and methods: thallium-201 (t1/2=3.04 d) in tl+ form was converted to tl3+ cation in presence of o3/6m hcl and di-isopropyl ether, controlle...

an octahedral cobalt(iii) complex, trans-[(me2bpb)co(bzlan)2]clo4 (1), with h2me2bpb = n,n’-(4,5-dimethyl-1,2-phenylene)dipicolinamide and bzlan = benzylamine, has been synthesized and characterized by elemental analyses, ir, uv-vis, and 1h nmr spectroscopy. the structure of this complex has been determined by x-ray crystallography. the me2bpb2– is a di-anionic tetradentate ligand furnishing a ...

Mn-(III)-chlorin, Photosynthesis, Photoreduction, Photooxidation, Hydroxylamine K3(Mn-(III)-chlorin e6)acetate, a water-soluble chlorophyll derivative with manganese as central atom was prepared. The influence of reducing agents, light, and bicarbonate on the oxida­ tion states of manganese in the chlorin complex was investigated. In alkaline solutions the central Mn3+ was reducible to Mn2+. Th...

The formation of diethyldithiocarbamate complexes with Mn(III), Fe(III), Co(III), Ni(II), Cu(II), Zn(II), Cd(II), Hg(II), Pb(II), and Bi(III) central atoms has been potentiometrically studied using a silver-complex electrode. Stability constants of complexes were determined in dimethyl sulfoxide and methanol as well as solubility products of Cu(II), Zn(II), and Cd(II) diethyldithiocarbamates in...

Manganese (Mn) oxides are among the most reactive sorbents and oxidants within the environment, where they play a central role in the cycling of nutrients, metals, and carbon. Recent discoveries have identified superoxide ([Formula: see text]) both of biogenic and abiogenic origin as an effective oxidant of Mn(II) leading to the formation of Mn oxides. Here we examined the conditions under whic...

Catalytic applications are widely used in both industrial and individual today due to their many advantages, especially the energy time they provide. For this purpose, coordination compounds have been synthesized catalytic performances investigated recent years.
 In study, Schiff base ligand, (N,N’-bis(2-hydroxy-3-methoxyphenylmethylidene)-2,6-pyridinediamine, BHMP), was with 2,6-diaminopy...