Vertically oriented single-walled carbon nanotubes (SWNTs) attract considerable attention, because it is expected as an ideal field emitter that can realize lower threshold voltage and higher electric current than microtips of Si or metals. In this study, we aim that SWNTs are vertically oriented using mesoporous silica film as a guide of the growth for SWNTs. For the orientation, the catalyst ...

Abstract The hydrogenation of nitriles to amines represents an important and frequently used industrial process due the broad applicability resulting products in chemistry life sciences. Despite existing portfolio catalysts reported for nitriles, development iron-based heterogeneous this is still a challenge. Here, we show that impregnation pyrolysis iron(II) acetate on commercial silica produc...

Silica-bonded N-propyldiethylenetriamine (7) is employed as a recyclable heterogeneous solid base catalyst for the synthesis of 2-amino-3,5-dicarbonitrile-6-thiopyridines through pseudo four-component condensation reaction between aromatic aldehydes, malononitrile, and 2-amino-thiophenol in refluxing ethanol. Silica-bonded N-propyldiethylenetriamine showed much the same efficiency when used in ...

Heterogeneous supported catalysts are often synthesized by impregnation or precipitation methods. Recently, melt infiltration has emerged as an alternative method that allows high metal loadings and eliminates the need for a solvent, but challenges arise regarding control over particle size distribution. In this work, synthesis of silver is explored. The narrow pore distribution chosen ordered ...

silica-bonded n-propyldiethylenetriamine (7) is employed as a recyclable heterogeneous solid base catalyst for the synthesis of 2-amino-3,5-dicarbonitrile-6-thiopyridines through pseudo four-component condensation reaction between aromatic aldehydes, malononitrile, and 2-amino-thiophenol in refluxing ethanol. silica-bonded n-propyldiethylenetriamine showed much the same efficiency when used in ...

The development of new advanced sustainable materials for heterogeneous catalysis requires control the structural parameters active sites. Mesoporous silica, especially SBA-15, has some unique and important features such as highly ordered mesopores, greater hydrothermal stability, wall thickness, large surface area, adjustable pore volume. All these properties render it a promising material cat...

This short review paper shows the significance of recombination of a photoexcited electron and a hole in conduction and valence bands, respectively, of a titania photocatalyst, since recombination has not yet been fully understood and has not been evaluated adequately during the past several decades of research on heterogeneous photocatalysis.

in this study, the microstructure and properties of foam glass obtained as a result of the interaction of the waste glass with sic as the foaming agent and fe2o3 as the oxidizing agent have been investigated using scanning electron microscopy (sem), as well as three-point bending and pycnometery tests. first, the temperature and optimized amount of sic for making foam glass was determined. the ...

The coating of solid surfaces with inorganic materials is a promising approach not only to impart various functionalities but also to modify physicochemical properties that are affected by the geometry/structure of the coating. In this study, a silica-hexadecyltrimethylammonium (silica-CTA) hybrid layer was deposited on monodispersed spherical particles composed of titania and octadecylamine (t...

We report the synthesis of Fe3O4@mSiO2 nanostructures of different meso-silica (mSiO2) shell thickness, their biocompatibility and behaviors for loading and release of a model drug ibuprofen. The composite nanostructures have superparamagnetic magnetite cores of 208 nm average size and meso-silica shells of 15 to 40 nm thickness. A modified Stöber method was used to grow the meso-silica shells ...